A new approach to isothermal enriching combined with separating perovskite phase from CaO–TiO2–SiO2–Al2O3–MgO melt by centrifugal force was investigated. Using a two-stage centrifugal separation process, the recovery ratio of Ti in the second concentrate was 99·34% and the tailings were 0·66%, thus demonstrating excellent Ti separation. These materials can be considered as suitable raw materials for titanium white and cement respectively.
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