The rate equation of hydrogen evolution reaction of spheroidal graphite cast iron with different pearlite area has been studied in sulphuric acid solutions at 298 K. The cathodic Tafel slope of −0·130 V/decade and the reaction order with respect to the activity of hydrogen ion of 1 are obtained by linear potential sweep technique. The rate equation of hydrogen evolution reaction does not depend on the area of pearlite. There is no difference in hydrogen evolution reaction mechanisms between pure iron and spheroidal graphite cast iron.
HorikawaKTakiguchiSIshizuY and KanazashiM: Boushoku-Gijutsu [Corrosion Engineering of Japan]19671653.
11.
UhligHH: ‘Corrosion and corrosion control’105–108; 1963New YorkJohn Wiley & Sons.
12.
FriendJA and GutmannF: in ‘The electrochemistry’750–779; 1965OxfordPergamon Press.
13.
SubramayanPK: in ‘Comprehensive treatise of electrochemistry Vol. 4’, (ed. BockrisJ O'Met al.), 411–429; 1981New YorkPlenum Press.
14.
ApplebyAJKitaHChemlaM and BronoëlG: in ‘Encyclopedia of electrochemistry of the elements Vol. IX Part A’, (ed. BardA J), 383–556; 1982New York, MarcelDekker.
15.
EnyoM: in ‘Comprehensive treatise of electrochemistry Vol. 7’, (ed. ConwayB Eet al.), 241–300; 1983New YorkPlenum Press.
16.
BardAJ and FaulknerLR: ‘Electrochemical methods’32–34; 1980New YorkJohn Wiley & Sons.
17.
ParsonsR: ‘Handbook of electrochemical constants’79; 1959LondonButterworths Scientific Publications.
18.
KortümG: ‘Treatise on electrochemistry’449–463; 1965AmsterdamElsevier.
