The electrode and the chemical reactions likely to occur on electrochlorination of sea water are reviewed. The levels of chlorine required to control fouling and the effects of pressure are also discussed. The reactions of chlorine with both common pollutants and chemical additions present in sea water are reviewed, as are the effects of chlorinated sea water on the corrosion of copper and ferrous alloys.
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References
1.
SchumacherM.(ed.): ‘Seawater corrosion handbook’;1979, Park Ridge, NJ, Noyes Data Corp.
2.
CampbellI. N. and SearleN. K.: Proc. Conf. 011 ‘Fouling and corrosion of metals in sea water’, Scottish Marine Biological Association, Dunstaffnage, April1982.
3.
FrancisR.: Mater. Perform., 1982, 21, (8), 44.
4.
TrotmanD. W.: Report NS 348, British Ship Research Association, 1972.
5.
LewisS. R. O.: Mater. Perform., 1982, 21, (9), 31.
GoldmanJ. C., WuimbyH. L., and CAPUZZOJ. M.: Water Res., 1979, 13, 315.
8.
PalinA. T.: Water Services, Jan. 1974, 7.
9.
LambT. J.: Proc. 3rd Int. Conf. on ‘Marine corrosion and fouling’, 995; 1973, Evanston, IL, North Western University Press.
10.
MangumD. C., ShepardB. P., and WILLIAMSJ. L.: Proc. 3rd Int. Conf. on ‘Marine corrosion and fouling’, 357; 1973, Evanston, IL, North Western University Press.
11.
KelsallG. H.: J. Appl. Electrochem., 1984, 14, 177.
12.
ShibataJ.KimuraM., UEDAK., and SEIKEY.: Proc. 3rd Int. Conf. on ‘Marine corrosion and fouling’, 964; 1973, Evanston, IL, North Western University Press.
13.
CottonJ. P.: Proc. Int. Conf. on ‘Marine corrosion and fouling’, 331; 1973, Evanston, IL, North Western University Press.
14.
ReinhartF. M.: Technical Note N-961, AD835104, Naval Civil Engineering Laboratory, Port Hueneme, CA, 1968
15.
RobertsonP. M., GnehmW., and PONTOL.: J. Appl. Electrochem., 1983, 13, 307.
16.
OldfieldJ. W. and ToddB.: Desalination, 1981, 38, 233.
17.
Erdey-GruzT.: ‘Kinetics of electrode processes’; 1972, London, Adam Hilger.
18.
CottonF. A. and WilkinsonG.: ‘Advanced inorganic chemistry’; 1962, New York, Interscience.
19.
JohnsonJ. D.(ed.):‘Disinfection. Water and wastewater’; 1975, Ann Arbor, MI, Science Publications.
20.
HelzG. R. and HsuR. Y.: Limnol. Oceanogr., 1978, 23, (5), 858.
21.
WongG. T. F. and DavidsonJ. A.: Water Res., 1977, 11, 971.
22.
DurrantP. J. and DurrantB.: ‘Introduction to advanced inorganic chemistry’; 1962, London, Longmans.
SeidellA.: ‘Solubilities of inorganic and metal organic compounds’, 3rd edn, Vol. 1; 1940, New York, Van Nostrand.
26.
FrancisR.: ‘The use of iron additions to sea water cooled condensers’, Report (Project 289), International Copper Research Association, New York, 1979; Research Report RRA1957, BNF Metals Technology Centre, Wantage, 1979.
27.
GilbertP. T.: Mater. Perform., 1982, 21, (2), 47.
28.
EffertzP. H. and FichteW.: Kraftwerkstechnik, 1977, 57, (2), 116.
29.
FrancisR.: Br. Corros. J., 1985, 20, 175.
30.
BemR. S. and GilbertP. T.: ‘Effect of hydrogen sulphide and sulphur on the behaviour of condenser tube materials in jet impingement and rotor tests’, Research Report RRA1095, British Non-Ferrous Research Association, London, 1955.
31.
SyrettB. C., MacdonaldD. D., and WINGS. S.: Corrosion, 1979, 35, (9), 409.
32.
JohannessonJ. K.: Analyst, 1958, 81, 155.
33.
LeeW. S. W., OldfieldJ. W., and TODDB.: Desalination, 1983, 44, 209.
34.
FrancisR.: Br. Corros. J., 1985, 20, 167.
35.
StewartW. C.and F. L. LA QUECorrosion, 1962, 8, 259.
AndersonD. B. and RichardsB. R.: J. Eng. Power, July1966.
44.
KainR. M. and LeeT. S.: in ‘Laboratory corrosion tests and standards’, STP866; 1985, Philadelphia, PA, ASTM.
45.
MalpasR. E., GallagherP., and SHONEE. B.: Proc. Conf. on ‘Chlorination of sea water systems and its effect on corrosion’, Birmingham, March1986, Society of Chemical Industry, Materials Preservation Group.
46.
ShoneE. B. and GallagherP.: Proc. Conf. on ‘High alloy steels for critical sea water applications’, Birmingham, March1985, Society of Chemical Industry, Materials Preservation Group.