An investigation of the carbon-supported iron phthalocyanine (Fe-Pc) catalyst for oxygen reduction reaction (ORR) in alkaline media and in hydrogen fuel cells is described. The non-noble metal Fe-Pc catalyst is shown to be a promising alternative to platinum for ORR in alkaline media, with onset potentials of ca. 15 mV higher and double the mass activity than that of Pt. The catalyst also showed lower peroxide generation at lower voltages than Pt when tested at a rotating ring disc electrode.
The effect of various parameters such as catalyst loading, catalyst layer thickness, fabrication technique, and ionomer on a hydrogen fuel cell performance using an alkaline electrolyte membrane made by radiation grafting is described. Peak power densities of the fuel cell with Pt/C oxygen reduction catalysts were greater than 100 mW/cm at 60 °C using air. The performance of the fuel cell with the Fe-Pc catalyst was inferior to that with the Pt catalyst giving approximately half the peak power density initially due to the thicker catalyst layer and instability in the quaternary ammonium environment. However, the performance of the Fe-Pc catalyst under fuel cell conditions was found to fall with time due to an interaction of the catalyst with the ion-exchange group of the membrane and the ionomer used in the catalyst layer.
ScottK.YuE. H.VlachogiannopoulosG.ShivareM.DuteanuN., ‘Performance of a direct methanol alkaline membrane fuel cell’J. Power Sources175 (1) (2008): 452–457.
9.
FujiwaraN.SiromaZ.YamazakiS.I.IoroiT.SenohH.YasudaK., ‘Direct ethanol fuel cells using an anion exchange membrane’J. Power Sources185 (2) (2008): 621–626.
10.
MatsuokaK.IriyamaY.AbeT.MatsuokaM.OgumiZ., ‘Alkaline direct alcohol fuel cells using an anion exchange membrane’J. Power Sources150 (2002): 27–31.
11.
DanksT. N.SladeR. C. T.VarcoeJ. R., ‘Comparison of PVDF- and FEP-based radiation-grafted alkaline anion-exchange membranes for use in low temperature portable DMFCs’J. Mater. Chem.12 (12) (2002): 3371–3373.
12.
DanksT. N.SladeR. C. T.VarcoeJ. R., ‘Alkaline anion-exchange radiation-grafted membranes for possible electrochemical application in fuel cells’J. Mater. Chem.13 (4) (2003): 712–721.
13.
KangJ. J.LiW. Y.LinY. A.LiX. P.XiaoX. R.FangS. B., ‘Synthesis and ionic conductivity of a polysiloxane containing quaternary ammonium groups’Polym. Adv. Technol.15 (1–2) (2004): 61–64.
14.
YiF.YangX. P.LiY. J.FangS. B., ‘Synthesis and ion conductivity of poly(oxyethylene) methacrylates containing a quaternary ammonium group’Polym. Adv. Technol.10 (7) (1999): 473–475.
15.
FangJ.ShenP. K., ‘Quaternized poly(phthalazinon ether sulfone ketone) membrane for anion-exchange membrane fuel cells’J. Membr. Sci.285 (1–2) (2006): 317–322.
16.
LiL.WangY. X., ‘Sulfonated polyethersulfone Cardo membranes for direct methanol fuel cell’J. Membr. Sci.246 (2) (2005): 167–172.
17.
PanY.HuangY. H.LiaoB.CongG. M., ‘Synthesis and characterization of aminated poly(2,6-dimethyl-1,4-phenylene oxide)’J Appl. Polym. Sci.61 (7) (1996): 1111–1115.
18.
WuL.XuT. W.WuD.ZhengX., ‘Preparation and characterization of CPPO/BPPO blend membranes for potential application in alkaline direct methanol fuel cell’J. Membr. Sci.310 (1–2) (2008): 577–585.
19.
WuL.XuT. W., ‘Improving anion exchange membranes for DMAFCs by inter-crosslinking CPPO/BPPO blends’J. Membr. Sci.322 (2) (2008): 286–292.
20.
LiL.WangY. X., ‘Quaternized polyethersulfone Cardo anion exchange membranes for direct methanol alkaline fuel cells’J. Membr. Sci.262 (1–2) (2005): 1–4.
21.
XingB.SavadogoO., ‘Hydrogen/oxygen polymer electrolyte membrane fuel cells (PEMFCs) based on alkaline-doped polybenzimidazole (PBI)’Electrochem. Commun.2 (10) (2000): 697–702.
22.
HouH.SunG.HeR.SunB.JinW.LiuH.XinQ., ‘Alkali doped polybenzimidazole membrane for alkaline direct methanol fuel cell’Int. J. Hydrog Energy33 (2002): 7172–7176.
23.
ModestovA. D.TarasevichM. R.LeykinA. Y.FilimonovV. Y., ‘MEA for alkaline direct ethanol fuel cell with alkali doped PBI membrane and non-platinum electrodes’J. Power Sources188 (2002): 502–506.
24.
YangC. C.ChiuS. J.ChienW. C., ‘Development of alkaline direct methanol fuel cells based on crosslinked PVA polymer membranes’J. Power Sources162 (1) (2006): 21–29.
25.
YangC. C.LeeY. J.ChiuS. J.LeeK. T.ChienW. C.LinC. T.HuangC. A., ‘Preparation of a PVA/HAP composite polymer membrane for a direct ethanol fuel cell (DEFC)’J. Appl. Electrochem.38 (10) (2008): 1329–1337.
26.
YangC. C.ChiuS. J.LeeK. T.ChienW. C.LinC. T.HuangC. A., ‘Study of poly(vinyl alcohol)/titanium oxide composite polymer membranes and their application on alkaline direct alcohol fuel cell’J. Power Sources184 (1) (2008): 44–51.
27.
LuoY.GuoJ.WangC.ChuD., ‘Quaternized poly(methyl methacrylate-co-butyl acrylate-co-vinylbenzyl chloride) membrane for alkaline fuel cells’J. Power Sources195 (2012): 3765–3771.
28.
JasinskiR., ‘A new fuel cell cathode catalyst’Nature4925 (1961): 1212–1213.
29.
BehretH.BinderH.SandstedeG.SchererG. G., ‘On the mechanism of electrocatalytic oxygen reduction at metal chelates: Part III. Metal phthalocyanines’J. Electroanal. Chem.117 (1) (1981): 29–42.
30.
Van Den BrinkF.VisscherW.BarendrechtE., ‘Electrocatalysis of cathodic oxygen reduction by metal phthalocyanines. Part II. Cobalt phthalocyanine as electrocatalyst: a mechanism of oxygen reduction’J. Electroanal. Chem.157 (2) (1983): 305–318.
31.
Van Den BrinkF.VisscherW.BarendrechtE., ‘Electrocatalysis of cathodic oxygen reduction by metal phthalocyanines. Part III. Iron phthalocyanine as electrocatalyst: experimental part’J. Electroanal. Chem.172 (1–2) (1984): 301–325.
32.
GojkovicS. L.GuptaS.SavinellR. F., ‘Heat-treated iron(III) tetramethoxyphenyl porphyrin supported on high-area carbon as an electrocatalyst for oxygen: I. Characterization of the electrocatalyst’J. Electrochem. Soc.145 (10) (1998): 3493–3499.
33.
JaouenF.LefevreM.DodeletJ. P.CaiM., ‘Heat-treated Fe/N/C catalysts for O2 electroreduction: are active sites hosted in micropores?’J. Phys. Chem. B110 (11) (2006): 5553–5558.
34.
LefevreM.ProiettiE.JaouenF.DodeletJ. P., ‘Iron-based catalysts with improved oxygen reduction activity in polymer electrolyte fuel cells’Science324 (5923) (2009): 71–74.
35.
MengH.JaouenF.ProiettiE.LefèvreM.DodeletJ.-P., ‘pH-effect on oxygen reduction activity of Fe-based electro-catalysts’Electrochem. Commun.11 (10) (2009):1986–1989.
36.
BarantonS.CoutanceauC.RouxC.HahnF.LégerJ. M., ‘Oxygen reduction reaction in acid medium at iron phthalocyanine dispersed on high surface area carbon substrate: tolerance to methanol, stability and kinetics’J. Electroanal. Chem.577 (2) (2005): 223–234.
37.
BezerraC. W. B.ZhangL.LeeK.LiuH.MarquesA. L. B.MarquesE. P.WangH.ZhangJ., ‘A review of Fe-N/C and Co-N/C catalysts for the oxygen reduction reaction’Electrochim. Acta53 (15) (2008): 4937–4951.
38.
MaJ.WangJ.LiuY., ‘Iron phthalocyanine as a cathode catalyst for a direct borohydride fuel cell’J. Power Sources172 (1) (2007): 220–224.
39.
ZhaoF.HarnischF.SchroderU.ScholzF.BogdanoffP.HerrmannI., ‘Application of pyrolysed iron(II) phthalocyanine and CoTMPP based oxygen reduction catalysts as cathode materials in microbial fuel cells’Electrochem. Commun.7 (12) (2005): 1405–1410.
40.
YuE. H.ChengS.LoganB. E.ScottK., ‘Electrochemical reduction of oxygen with iron phthalocyanine in neutral media’J. Appl. Electrochem.39 (5) (2009): 705–711.
41.
MartinJ. J.NeburchilovV.WangH.QuW., ‘A review on air cathodes for zinc-air fuel cells’J. Power Sources195 (5) (2010): 1271–1291.
42.
ChenR.LiH.ChuD.WangG., ‘Unraveling oxygen reduction reaction mechanisms on carbon-supported fe-phthalocyanine and co-phthalocyanine catalysts in alkaline solutions’J. Phys. Chem. C113 (48) (2009):20689–20697.
43.
ChengH.ScottK.LovellK. V.HorsfallJ. A.WaringS. C., ‘Evaluation of new ionexchange membranes for direct borohydride fuel cells’J. Membr. Sci.288 (2002): 168–174.
44.
HorsfallJ. A.LovellK. V., ‘Synthesis and characterisation of sulfonic acid-containing ion-exchange membranes based on hydrocarbon and fluorocarbon polymers’J. Eur. Polym38 (2002): 1671–1682.
45.
VarcoeJ. R.SladeR. C. T.YeeE. L. H., ‘An alkaline polymer electrochemical interface: A breakthrough in application of alkaline anion-exchange membranes in fuel cells’Chem. Commun. (13) (2006): 1428–1429.
46.
WangY. G.KoraiY.MochidaI., ‘Carbon disc of high density and strength prepared from synthetic pitch-derived mesocarbon microbeads’Carbon37 (1991): 1049–1057.
47.
LiuS.JiangX.ZhuoG., ‘In situ chemical formation of iron phthalocyanine (Fe-Pc) monolayer on the surface of magnetite nanoparticles’New J. Chem.31 (2002): 916–920.
48.
AlvaroM.CarbonellE.Espla’M.GarciaH., ‘Iron phthalocyanine supported on silica or encapsulated inside zeolite Y as solid photocatalysts for the degradation of phenols and sulfur heterocycles’Appl. Catal. B, Environ.57 (2002): 37–42.
49.
JiangL.HsuA.ChuD.ChenR., ‘Oxygen reduction on carbon supported Pt and PtRu catalysts in alkaline solutions’J. Electroanal. Chem.629 (1–2) (2009): 87–93.
