A straightforward strategy is reported for chiral discrimination in a specified carotenoid using a CD band, which is insensitive to conformational changes, computed by quantum chemical calculation.
NoackK, ThomsonAJ. (1979) Conformation and optical activity of all-trans, mono-cis, and di-cis carotenoids: temperature dependent circular dichroism. Helvetica Chimica Acta, 621902-1921.
5.
GoodwinTW. (1984) In Biochemistry of the Carotenoids, Chapman and Hall, London, Vol. 2: Animals. 2nd Ed;
6.
MatsunoT, HiraoS. (1989) Marine lipid classes. In Marine Biogenic Lipids, Fats, and Oils.Ackman RG. (Ed). CRC Press, Boca Raton, FL, Vol. 1, pp. 251-388;
7.
TsushimaM, MatsunoT. (1990) Comparative Biochemistry and Physiology, Part B: Biochemistry & Molecular Biology, 96B801-810;
8.
MaokaT, MatsunoT. (1989)Diastereomeric resolution of carotenoids. IV. Carotenoids with a 4-hydroxy-β-end group. Journal of Chromatography, 482189-195;
9.
HaagA, EugsterCH. (1985) Synthesis of optically active carotenoids with (R)-4-hydroxy β-end groups. Helvetica Chimica Acta, 681897-1906;
10.
MaokaT, AraiA, ShimizuM, MatsunoT. (1986)The first isolation of enantiomeric and meso-zeaxanthin in nature. Comparative Biochemistry and Physiology, Part B: Biochemistry & Molecular Biology, 83B121-124;
11.
IkunoY, MaokaT, ShimizuM, KomoriT, MatsunoT. (1985)Direct diastereomeric resolution of carotenoids. II. All ten stereoisomers of tunaxanthin (∊, epsi;-carotene-3,3′-diol). Journal of Chromatography, 328387-391.
12.
MatsunoT, AkitaT, HaraM. (1973)Carotenoid pigments of Japanese anchovy. Nippon Suisan Gakkaishi, 3951-54.
