A new secobeyerenoic acid mono ester, ent-2,3-secobeyer-15-en-2,3-dioic acid, 3-methyl ester was isolated from the heartwood of Spirostachys africana and identified using spectroscopic methods. The mono ester was also prepared using two methods; by reacting the known diacid, ent-2,3-secobeyer-15-en-2,3-dioic acid with 1.5 mole equivalency of diazomethane, and methanolysis of ent-2,3-secobeyer-15-en-2,3-dioic anhydride.
De BoerThJ, BackerHJ. (1963) Diazomethane. In Organic Synthesis Collections, 4, 250–253.
3.
SabithaG, SrividyaR, YadavJS. (1999) Ring opening of cyclic anhydrides: Synthesis of achiral half–esters using Lewis acids. Tetrahedron, 55, 4015–4018.