The mixed-metal mixed-halide complex [CuPbBrlL2]2 has been prepared by the direct interaction of zerovalent copper with lead halides and 2-dimethylaminoethanol (HL) in dmso and has been characterized by X-ray crystallography; the structure shows a layer arrangement of the tetranuclear metal units through the μ3-halogen bridging.
References
1.
See, for example: LehnJ.-M., Angew. Chem., Int. Ed. Engl., 1988, 27, 89; O. Kahn, Molecular Magnetism, VCH Publishers, New York, 1993; Th. A. Kaden, in Transition Metals in Supramolecular Chemistry, ASIC 448, ed. L. Fabbrizzi and A. Poggi, Kluwer Academic Publishers, Dordrecht, 1994, p. 211; D. W. Stephan, Coord. Chem. Rev., 1989, 95, 41.
2.
KovbasyukL. A., VassilyevaO. Yu., KokozayV. N., LinertW., ReedijkJ., SkeltonB. W., and OliverA. G.J. Chem. Soc., Dalton Trans., 1998, 2735 and references therein.
3.
VassilyevaO. Yu., KovbasyukL. A., KokozayV. N., SkeltonB. W., and LinertW.Polyhedron, 1998, 17, 85.
4.
HathawayB. J., and BillingD. E., Coord. Chem. Rev., 1970, 5, 143.
5.
TEXSAN, Version 1.7-1, Molecular Structure Corporation, The Woodlands, TX, 1985, 1992, 1995.
6.
SheldrickG. M., SHELXL 93, Program for Crystal Structure Refinement, University of Göttingen, Göttingen, 1993.
