Hydroaminomethylation of styrene with morpholine catalysed by a cationic rhodium complex with a P,N ligand possessing a hydroxy group and the influence of the temperature on the chemo- and regio-selectivity are described.
References
1.
ReppeW., and VetterH., Liebigs Ann. Chem., 1953, 582, 133.
2.
RischeT., and EilbrachtP., Synthesis, 1997, 1331.
3.
MolinaP., ArquesA., GarciaA., and Ramirez de ArellanoM. C., Eur. J. Inorg. Chem., 1998, 1359 and refs. therein.
4.
KostasI. D., and ScrettasC. G., J. Organomet. Chem., 1999, 585, 1.
5.
BaigT., and KalckP., J. Chem. Soc., Chem. Commun., 1992, 1373.
6.
BaigT., MolinierJ., and KalckP., J. Organomet. Chem., 1993, 455, 219.
