Trinuclear palladium(II) complexes of the type [Pd3X2(μ-Y)2(μ-pz)2(PR3)2] [X = CI or Ph; Y = CI, SPh, SC6F5 or SC6H4C1-4; PR3 = PPh3 or P(tol)3] are prepared and characterised by elemental analyses, NMR (1H and 31P-{1H}) and FAB mass spectral data.
References
1.
JainV. K., Curr. Sci., 1990, 59, 143.
2.
WernerH., Adv. Organomet. Chem., 1981, 19, 155; B. Chaudret, B. Belavaux and R. Poilblanc, Coord. Chem. Rev., 1988, 86, 191; D. G. Smith and H. B. Gray, Coord. Chem. Rev., 1990, 100, 169; G. K. Anderson, Adv. Organomet. Chem., 1993, 35, 1; K. Umakoshi and Y. Sasaki, Adv. Inorg. Chem., 1993, 40, 187.
3.
MatsumatoK., SaigaN., TanakaS., and OoiS., J. Chem. Soc., Dalton Trans., 1991, 1265.
4.
PadillaE. M., and JensenC. M., Polyhedron, 1991, 10, 89.
5.
CorrondoM. A. A. F. De C. T., and SkapskiA. C., J. Chem. Soc., Chem. Commun., 1976, 410; A. C. Skapski and M. L. Smarl, J. Chem. Soc., Chem. Commun., 1970, 658.
6.
BalchA. L., BoehmJ. R., HopeH., and OlmsteadM. M., J. Am. Chem. Soc., 1976, 98, 1431; P. M. Bailey, E. A. Kelly and P. M. Maitlis, J. Organomet. Chem., 1978, 144, C52.
7.
UsonR., ForniesJ., TomasM., MenjonB., CarnicerJ., and WelchA. J., J. Chem. Soc., Dalton Trans., 1990, 151; R. D. Adams, J. E. Babin and M. Tasi, Organometallics, 1987, 6, 1717.
8.
UsonR., ForniesJ., UsonM. A., TomasM., and IbanezM. A., J. Chem. Soc., Dalton Trans., 1994, 401.
9.
BasatoM., GrassiA., and ValleG., Organometallics, 1995, 14, 4439.
10.
NarayanS., JainV. K., and ButcherR. J., Polyhedron, 1998, 17, 2037.
11.
SinghalA., JainV. K., and ManisekranT., unpublished results [Pd-P 2.23; Pd-Cl = 2.67, 2.32, 2.43 Å].
12.
GrigsbyW. J., and NicholsonB. K., Acta Crystallogr., Sect. C, 1992, 48, 362; P. A. Chaloner, S. Z. Dewa and P. B. Hitchcock, Acta Crystallogr., Sect. C, 1995, 51, 232.
13.
ElduqueA., OroL. A., PinillosM. T., TejelC., TiripicchioA., and UgozzoliF., J. Chem Soc., Dalton Trans., 1991, 2807.
14.
PinillosM. T., ElduqueA., MartinE., NavarroN., LahojF. J., LopezJ. A., and OroL. A., Inorg. Chem., 1995, 34, 111.
15.
JainV. K., KannanS., ButcherR. J., and JasinskiJ. P., J. Chem. Res. (S), 1996, 284.
16.
JainV. K., and KannanS., Polyhedron, 1992, 11, 27.
17.
GrushinV. V., and AlperH., Organometallics, 1993, 12, 1890.
18.
PinillosM. T., TejelC., OroL. A., ApredaM. C., CanoF. C., and Foces-FocesC., J. Chem., Soc., Dalton Trans., 1989, 1133.
19.
UsonR., GimenoJ., OroL. A., Martinez-De IlarduyaJ. M., and CabezaJ. A., J. Chem. Soc. Dalton Trans., 1983, 1729.