2-(Triphenylphosphoranylideneamino)tropone is synthesized for the first time and treated with heterocumulenes to give novel cyclohepta-annulated heterocycles in good yields.
References
1.
Part 32 of the reaction of (vinylimino)phosphoranes and related compounds. Part 31: YamamotoH., KobayashiT., and NittaM., Heterocycles, 1998, 48, 1903.
2.
For recent reviews see (a) GololobovY. G., and KasukhinL. F., Tetrahedron, 1992, 48, 1353; (b) S. Eguchi, Y. Matsushita and K. Yamashita, Org. Prep. Proced. Int., 1992, 24, 209; (c) M. Nitta, Rev. Heteroat. Chem., 1993, 9, 87; (d) P. Molina and M. J. Vilaplana, Synthesis, 1994, 1197; (e) H. Wamhoff, G. Richardt and S. Stolben, Adv. Heterocycl. Chem., 1995, 64, 159.