Polysiloxanes containing grafted and/or end-capped functional groups, due to their specific properties, receive attention in various industrial ap plications. This paper presents the synthesis and development of new poly functional silicones. For example, the grafting of selected organofunctional groups onto silicone backbones allows us to increase the hydrophobic-oleophobic perma nence or hydrophilic softness properties for textile treatments. To achieve these properties, new synthetic routes using novel organometallic catalysts and specific monomers have been developed.
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