Abstract
A simple and convenient method was explored for glycolyzing polycarbonate (PC). Different from the harsh conditions in traditional methods, this method can be performed under moderate condition by using 1, 4-dioxane as the solvent and zinc acetate as the catalyst. The recycling of PC has been extensively studied for the recovery of bisphenol-A, whereas in this study, the controllable glycolysis of PC could be achieved at various reaction conditions. The glycolysis products with different molecular weight can be used to copolymerize with other monomers to prepare copolymers. This simple chemical technology will certainly facilitate the cyclic utilization of PC.
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References
1.
Antonakou E.V.
, and
Achilias D.S.
, Waste and Biomass Valorization , 4 , (2013 ), 9 .
2.
Chiu S.J.
,
Chen S.H.
, and
Tsai C.T.
, Waste Management , 26 , (2006 ), 252 .
3.
Jang B.N.
, and
Wilkie C.A.A.
, Polymer Degradation and Stability , 86 , (2004 ), 419 .
4.
Zhou W.J.
,
Yang H.
, and
Zhou J.
, Journal of Analytical and Applied Pyrolysis , 78 , (2007 ), 413 .
5.
Zhao W.
,
Li B.
, and
Xu M.J.
, Journal of Macromolecular Science, Part B: Physics , 51 , (2012 ), 2141 .
6.
Tsintzou G.P.
, and
Achilias D.S.
, Waste and Biomass Valorization , 4 , (2013 ), 3 .
7.
Watanabe M.
,
Matsuo Y.
,
Matsushita T.
,
Inomata H.
,
Miyake T.
, and
Hironaka K.
, Polymer Degradation and Stability , 94 , (2009 ), 2157 .
8.
Huang Y.Y.
,
Liu S.X.
, and
Pan Z.Y.
, Polymer Degradation and Stability , 96 , (2011 ), 1405 .
9.
Jung J.H.
,
Ree M.
, and
Kim H.
, Catalysis Today , 115 , (2006 ), 283 .
10.
Liu F.S.
,
Li L.
,
Yu S.T.
,
Lv Z.G.
, and
Ge X.P.
, Journal of Hazardous Materials , 189 , (2011 ), 249 .
11.
Liu F.S.
,
Li Z.
,
Yu S.T.
,
Cui X.
,
Xie C.X.
, and
Ge X.P.
, Journal of Polymers and Environment , 17 , (2009 ), 208 .
12.
Kim D.
,
Kim B.K.
,
Cho Y.
,
Han M.
, and
Kim B.S.
, Industrial & Engineering Chemistry Research , 48 , (2009 ), 6591 .
13.
Nikje M.M.A.
, Polimery , 56 , (2011 ), 381 .
14.
Mehr M.Y.
,
Driel W.D.
,
Jansen K.M.B.
,
Deeben P.
,
Boutelje M.
, and
Zhang G.Q.
, Optical Materials , 35 , (2013 ), 504 .
15.
Diepens M.
, and
Gijsman P.
, Polymer Degradation and Stability , 95 , (2010 ), 811 .
16.
Diepens M.
, and
Gijsman P.
, Polymer Degradation and Stability , 92 , (2007 ), 397 .
17.
Diepens M.
, and
Gijsman P.
, Polymer Degradation and Stability , 93 , (2008 ), 1383 .
18.
Huang J.
,
Huang K.
,
Zhou Q.
,
Chen L.
,
Wu Y.Q.
, and
Zhu Z.B.
, Polymer Degradation and Stability , 91 , (2006 ), 2307 .
19.
Artham T.
,
Mohanalakshmi N.
,
Paragi-Vedanthi P.P.
, and
Doble M.
, Enzyme Microbial Technology , 48 , (2011 ), 71 .
20.
Liu F.S.
,
Li Z.
,
Yu S.T.
,
Cui X.
, and
Ge X.P.
, Journal of hazardous Materials , 174 , (2010 ), 872 .
21.
Shukla S.R.
, and
Harad A.M.
, Journal of Applied Polymer Science , 97 , (2005 ), 513 .
22.
Pingale N.D.
,
Palekar V.S.
, and
Shukla S.R.
, Journal of Applied Polymer Science , 115 , (2010 ), 249 .
23.
Kim D.
,
Kim B.K.
,
Cho Y.
,
Han M.
, and
Kim B.S.
, Industrial & Engineering Chemistry Research , 48 , (2009 ), 685 .
24.
Chen L.
,
Wu Y.Q.
,
Ni Y.H.
,
Huang K.
, and
Zhu Z.B.
, Journal of Chemical Industry and Engineering (China) , 55 , (2004 ), 1787 .
25.
Wang X.Y.
,
Chen M.J.
, and
Cui Y.
, Gansu Science and Technology , 29 , (2013 ), 18 .