Production,deformation and magnetorheological characteristics of the alginate/chitosan hydrogel magnetic microspheres

Abstract

To improve dispersion stability and magnetorheological (MR) characteristics of carbonyl iron (CI) particles, we proposed novel hydrogel magnetic microspheres (MPs) dual-coated with alginate (AL) and chitosan (CTS) for the first time. The double-network structures formed by biological crosslinking and chelation reactions are capable to enhance its own structural stability and mechanical properties. The structural characterization, MR properties, and dispersion stability for different MPs were investigated. Additionally, the swelling behaviors were studied by swelling the dried MPs in the deionized water and sodium chloride solution, respectively. The results showed that the AL/CTS hydrogel core/shell MPs displayed the advantages of simple manufacturing, superior MR properties and deformability compared to pure micron-sized CI particles, indicating the improved dispersion stability of the MR fluids compared to that of the pure CI particles-based MR fluids. The introduction of double network structures with natural biopolymers will provide a new thought for the development of MR materials.