The new bimetallic cluster [Fe2(CO)4(μ,η2-OCC6H5)(μ4,η3-CH3C(CH2PPh2)2CH2PPh)] 3 has been synthesised from reaction between Fe3(CO)121 and the tripodal polyphosphine compound CH3C(CH2PPh2)3 (1,1,1-tris(diphenyl-phosphinomethyl)ethane: triphos) 2. The structure of cluster 3 has been established by single-crystal X-ray diffraction method.
SchmidG., Clusters and Colloids: From Theory to Applications; VCH, Weinheim, 1994.
2.
CifuentesM.P., HumphreyM. G., McGradyJ. E., SmithP. J., StrangerR., MurrayK. S., and MoubarakiB., J. Am. Chem. Soc., 1997, 119, 2647.
3.
LucasN.T., BlitzJ. P., PetrieS., StrangerR., HumphreyM. G., HeathG. A., and Otieno-AlegoV., J. Am. Chem. Soc., 2002, 124, 5139.
4.
AdamsR.D., and CottonF. A., Catalysis by di- and polynuclear metal cluster complexes; Wiley-VCH, New York, 1998.
5.
BraunsteinP., OroL. A., and RaithbyP. R., In Metal Clusters in Chemistry; BraunsteinP., OroL. A., and RaithbyP. R., eds, Wiley-VCH, Weinheim, Germany, Vol. 2, 1999.
6.
OverettM.J., HillR. O., and MossJ. R., Coord. Chem. Rev., 2000, 206-207, 581.
7.
GatesB.C., J. Mol. Catal. A: Chem., 2000, 163, 55.
8.
PaulH., BhaduriS., and LahiriG. K., Organometallics, 2003, 22, 3019.
9.
NagashimaH., ItonagaC., YasuharaJ., MotoyamaY., and MatsubaraK., Organometallics, 2004, 23, 5779.
10.
BianchiniC., HerreraV., JimenezM. V., MeliA., Sanchez-DelgadoR. A., and VizzaF., J. Am. Chem. Soc., 1995, 117, 8567.
11.
BianchiniC., MeliA., MonetiS., OberhauserW., VizzaF., HerreraV., FuentesA., and Sanchez-DelgadoR. A., J. Am. Chem. Soc., 1999, 121, 7071.
12.
GibsonD.H., HeH., and MashutaM. S., Organometallics, 2001, 20, 1456.
