A review of modem methods of chemical analysis for the characterisation of lamps and lamp materials is presented. The general categories which are discussed are in situ emission and absorption spectroscopy, electrical diagnostics of trace impurities, gas analysis by mass spectrometry and gas chromatography, vapour pressure and vapour composition measurements, surface analysis and x-ray methods, thermal analysis, and instrumental and wet-chemical methods for elemental analysis in solids. Numerous examples of the application of these methods to lamps and lamp materials are presented.
Get full access to this article
View all access options for this article.
References
1.
High Temperature LampChemistry Proc. Electrochem. Soc. ed. Zubler E G 85(2) (1985)
2.
High Temperature LampChemistry II Proc. Electrochem. Soc. ed. Zubler E G 88(4) ( 1988)
3.
Proc. Fifth Int. Symp. Sci. Technol. Light Sources , York, England (September 1989 )
Proc. Third Int. Symp. Sci. Technol. Light Sources , Toulouse, France (April 1983)
6.
van den Hoek W.J.Diagnostic methods in lamp researchProc. Third Int. Symp. Sci. Technol. Light Sources, Toulouse , France pp 18-21 (April 1983)
7.
Fischer E.Axial segregation of additives in mercury-metal-halide arcsJ. Appl. Phys.47(7) 2954-2960 (1976)
8.
Rothwell H L. Jr and Keeffe W.M A direct reading polychromator for real time diagnostics of HID lampsJ. Illum. Eng. Soc . 10(1) 40-46(1980)
9.
Hirayama C., Singleton J.H. and Wolfe A.L.Emission spectra, temperature, and voltage measurements of HPS and HPM lamps at start-upJ. Illum. Eng. Soc.10(2) 90-95 (1981)
van Erk W. and Rietveld T.The reaction of rare-earth metal iodides with the silica wall in metal halide discharge lampsPhilips J. Res. 42(1) 102-118 (1987)
12.
Fischer E.Formation of free iodine in metal halide lampsProc. Electrochem. Soc. ed. Zubler E G 88(4) 90-95 (1988)
13.
Groves R D and Bhattacharya A K. Evaporation rates from an oxide coated tungsten electrode in low pressure discharge devices Proc. Fifth Int. Symp. Sci. Technol. Light Sources, York, England pp243-244 (September 1989)
14.
Popp H-P. and Ascher R.Impurities in high pressure mercury discharge lampsProc. Fifth Int. Symp. Sci. Technol. Light Sources, York , England pp 121-122 (September 1989)
15.
Hannsler R.L. and Davenport J.M A new low wattage hatide lamp processJ. Illum. Eng. Soc.15(1) 109-122 (1985)
16.
Mochimaru S. , Sasaki H. and Inukai S.Reducing impurity gases in miniature metal halide lampsJ. Illum. Eng. Soc.14(l) 264-273 (1984)
17.
Sulcs J Unpublished results
18.
Eppig H J. Appraisal of incandescent lamp filling gas purity J . Illum . Eng. Soc. 12(1) 34-39 (1982)
19.
Zaengel T. and Groiss E. Light scattering from metal halide arcs P roc. Third Int. Symp. Sci. Technol. Light Sources, Toulouse , France pp110-111 (April 1983)
Bigio L. Laser diagnostic density measurements of Hg(63P0,1,2) in a low-pressure Hg-Ar dischargeProc. Electrochem. Soc. ed. Zubler E G 88(4) 313-324 (1988)
22.
Bigio L. and Dakin J T.Radial variations of Hg(63PJ) in a narrow-diameter low-pressure Hg-Ar dischargeJ. Appl. Phys. 65(1) 375-378 (1989)
23.
Bigio L.Density measurements of Hg(63P0,1,2) in a discharge using saturated laser absorption and hook methodsJ. Appl. Phys. 63(11) 5259-5269 (1988)
24.
Allen G.R., Lagushenko R., Maya J. and Keeffe W.M.Measurement of sodium groundstate density profile in a metal-halide lamp using laser absorption spectroscopyJ. Illum. Eng. Soc.16(2) 13-20 (1987)
25.
Devonshire R. The application of spatially resolving laser diagnostic techniques to the study of operating light sources and related systems Proc. Electrochem. Soc. ed. Zubler E G 88(4) 281-312 (1988)
26.
Bhattacharya A K. and Hlahol P G. Laser induced fluorescence studies of Ba loss from fluorescent lamp electrodes with conventional ballastsProc. Fourth Int. Symp. Sci. Technol. Light Sources, Karlsruhe, Germany pp223-224 (April 1986)
27.
Bhattacharya A K. and Awadallah A S. Dynamics of the neutral and ionized barium atoms in the vicinity of fluorescent lamp electrodes Proc. Fifth Int. Symp. Sci. Technol. Light Sources, York, England pp 233-234 (September 1989)
28.
Hilbig R. and Chittka U. Barium diagnostics in front of heated fluorescent lamp electrodes Proc. Fifth Int. Symp. Sci. Technol. Light Sources, York, England pp245-246 (September 1989)
29.
Woodward J R.An aluminum transport cycle observed by multi-photon LIF in operating halogen lampsProc. Fifth Int. Symp. Sci. Technol. Light Sources, York, England pp197-198 (September 1989)
Gungle W.C. and WaymouthJ F A selective getter for metal halide lampsJ. Illum. Eng. Soc.1(3) 222-226 (1972)
32.
Drop P.C., de Groot J J., Jack A G. and Rouweler G C JSome aspects of the tin halide molecular arcLighting Res. Technol. 6(4) 212-216 (1974)
33.
Mucklejohn S A. Chemical problems and limitations in HID lamps Proc. Electrochem. Soc. ed. Zubler E G 88(4) 1-17 (1988)
34.
Zhu Y H., Wu C.R., Yuan C. and Wang H.O.Residual gases in the outer jacket of metal halide lampsProc. Fourth Int. Symp. Sci. Technol. Light Sources, Karlsruhe , Germany pp113-114 (April 1986)
35.
Zong G., Zhou H., Wu R. and Liu C.Mass spectrometric analysis of getters for electric incandescent lampsZhenkorag Kexue Yu Jishu7(6) 407-411 (1987)
36.
Koprio J.A. , Gaug H. and Eppler H.Analysis of small gas volumes: inclusions in glass, gas filled lamps and sealed semiconductor packagesInt. J. Mass Spectrom. Ion Phys.4823-26 (1983)
37.
37 Cope D M Unpublished results
38.
Gungle W C. and Waymouth J F. US Patent No. 3 519 864 (7 July 1970)
39.
Waymouth J F. , Keeffe W M. and Gungle W C. US Patent No. 3 737 710 (5 June 1973)
40.
Thompson B.Fundamentals of Gas Analysis by Gas Chromatography ( Palo Alto, CA: Varian Associates) ( 1977 )
41.
Castello G. and Pesente P. Analysis of gaseous impurities in the filling gas af fluorescent lamps by gas chromatography with a helium detector P roc. Fourth Int. Conf. Residual Gases Electron Tubes pp 143-151 (1971)
42.
Biro E. and Reznik S.GC analysis of the gas filling of incandescent lamps: determination of oxygen impurity in argon Chrontatographia 26 413-416 (1988)
43.
Nagy L., Biro E. and Balla J. Gc analysis of gas in halogen lamps using a new sampling device Chrmnatographia26( 1) 34-36 (1988)
44.
Smosarska E. and Wilenska E. Chromatographic determination of dibromomethane in the gas used as a filling of halogen incandescent lamps C hem, Anal. (Warsaw) 29(6) 759-762 (1984)
45.
Bigio L.FTIR diagnostics on tungsten-halogen lampsProc, Fifth Int. Symp. Sci. Technol. Light Sources, York , England pp199-200 (September 1989)
46.
Hilpert K. Complexation in metal halide vapour-a review Proc. Electrochem. Soc. ed. Zubler H G 88(4) 36-69 (1988)
47.
Hilpert K.Complexation in metal halide vapours-a reviewJ. Electrochem. Soc. 136(7) 2099-2108 (1989 )
48.
Popovic A., Marsel J. and Kaposi O.Mass spectrometric studies of the attack of tungsten by bromine, chlorine and oxygenProc. Fourth Int. Symp. Sci. Technol. Light Sources, Karlsruhe, Germany pp241-242(April 1986 )
49.
Popovic A., Marsel J. and Kaposi O. Thermal desorption of bromine from polycrystalline tungsten surface Proc. Electrochem. Soc. ed. Zubler E G 85(2) 78-94 (1985)
50.
Datta R K. Emission and sealing materials chemistry of high-pressure sodium (HPS) lampProc. Electrochem. Soc. ed. Zubler E G 88(4) 220-239 (1988)
51.
Bencze L., Popovic A. and Kaposi O.The vaporization behaviour of pure BaO and alkaline earth containing mixed oxidesProc. Fifth Int. Symp. Sci. Technol. Light Sources, York, England pp 235-236 (September 1989)
52.
Russell T D.The vapor phase composition above the CdI2-NaI and the ThI4-NaI systems Proc. Electrochem. Soc. ed Zubler E G 85(2) 204-217 (1985)
53.
O'Brien N W. and Mucklejohn S A.A study of the vapour-phase equilibria over tin(II) chlorideJ. Chem. Thermodynamics191065-1077 (1987)
54.
Mucklejohn S.A. and O'Brien N W.The vapour pressure of tin(II) chloride and the standard molar Gibbs free energy change for formation of SnCl2(g) from Sn(g) and Cl2(g)J. Chem. Thermodynamics191079-1085 (1987)
55.
Mucklejohn S A., O'Brien N W. and Brumleve T R.High-purity iron(II) iodide: preparation, vapor pressure and vapor composition, 792 to 1138 KJ. Phys. Chem.89(11) 2409-2415 (1985 )
56.
Mucklejohn S A., O'Brien N W. and Brumleve T R. Vapor pressure and thermochemical parameters of metal halides: InCl and TlBrProc. Fifth Int. Symp. Sci. Technol. Light Sources, York, England pp119-120 (September 1989)
57.
Brumleve T R., Mucklejohn S A. and O'Brien N W.The preparation and vapour pressures of the indium(I) halides and the standard molar Gibbs free energy change for formation of InX from In(g) and X2(g), (X = Cl,Br, or I)J. Chem. Thermodynamics211193-1206 (1989)
58.
Fischer E., Kaiser R. and Niemann U.Thermochemical data of scandium halides evaluated from vapour pressure measurements and reactions with quartzProc. Fifth Int. Symp. Sci. Technol. Light Sources, York, England pp111-112 (September 1989)
59.
Hilpert K., Miller M. and Sai-Baba M.Chemical vapour transport and complexation in the NaI-ScI3 systems Proc. Fifth Int. Symp. Sci. Technol. Light Sources , York, England pp113-114 (September 1989)
60.
Fields M., Devonshire R., Edwards H G M. and Fawcett V.Laser-Raman spectroscopy of metal halide vapours at high temperatureProc. Fifth Int. Symp. Sci. Technol. Light Sources , York, England pp109-110(September 1989)
61.
Niemann U. Solid compounds in halogen-filled incandescent lamps Proc. Fourth Int. Symp. Sci. Technol. Light Sources, Karlsruhe, Germany pp181-182 (April 1986)
62.
Dittmer G. and NiemannU The influence of solid phases on transport cycles in halogen-filled incandescent lampsPhilips J. Res.42(1) 41-57 (1987)
63.
Dittmer G. and NiemannU Evaluation of thermodynamic data on zirconium and hafnium halides and oxyhalides by means of transport experimentsPhilips J. Res.42(1) 15-40 (1987)
64.
O'Brien N W. and Mucklejohn S A. Preliminary report on the examination of electrode erosion by the transpiration technique Proc. Fourth Int. Symp. Sci. Technol. Light Sources, Karlsruhe, Germany pp233-234 (April 1986)
65.
O'Brien N W. and Mucklejohn S A.Examination of electrode erosion by the transpiration techniqueLighting Res. Technol . 18(3) 133-137 (1986)
66.
O'Brien N W. The chemical corrosion of hot tungsten by tin(II) chloride vapour and oxygenProc. Electrochem. Soc. ed. Zubler E G 88(4) 22-35 (1988)
67.
Fields M., Mucklejohn S A. and O'Brien N W.A technique for the study of the interactions of metal halides with gaseous impuritiesProc. Fifth Int. Symp. Sci. Technol. Light Sources, York, England pp107-108 (September 1989)
68.
Duncan M., Meads J., Devonshire R., O'Brien N.W. and Mucklejohn S A.Fluid flow modelling of a modified transpiration experiment designed to investigate electrode corrosionProc. Fifth Int. Symp. Sci. Technol. Light Sources, York, England pp 105-106 (September 1989)
69.
Adams F., Gijbels R. and Van Grieken R.Inorganic Mass Spectrometry in Chemical Analysis Vol. 95 ed. Winefordner J D ( New York: Wiley) (1988 )
70.
Evans C A., Jr Surface and thin film compositional analysisAnal. Chem. 47(9) 818A-829A and 855A-866A ( 1975)
71.
Brundle C R. Ultra-high vacuum techniques of surface characterization in Industrial Applications of Surface Analysis ed. Casper L A and Powell C J ACS Symposium Series 199 (Washington, DC: American Chemical Society) pp 13-32 (1982)
72.
Hercules D M.Challenges in surface analysisAnal. Chem. 50(8) 734A-744A ( 1978)
73.
Benninghoven A., Rüdenauer F G. and Werner H W.Secondary Ion Mass Spectrometry in Chemical Analysis Vol. 86 ed. Elving P J and Winefordner J D (New York : Wiley) (1987)
74.
Jenkins R., Gould R.W. and GedckeD Quantitative X-ray Spectrometry (New York: Dekker) (1981)
75.
Jenkins R.X-ray Fluorescence Spectrometry in Chemical Analysis Vol. 99 ed. Winefordner J D and Kolthoff I M (New York: Wiley) (1988)
76.
Birks L S.Electron Probe Microanalysis in Chemical Analysis Vol. 17 ed. Elving P J and Kolthoff I M (New York: Interscience) (1963)
77.
Speros D.M. , Datta R.K. and Lynch D.A.Chemical reactivity in halide discharges: effects of condensed phases and common componentsJ. Electrochem. Soc. 128(4) 778--786 (1981)
78.
Hing P. Interaction of alkali metal and halide vapors with ceramic materials J. lllum. Eng. Soc. 10(4) 194-203 (1981)
79.
Mulder B J. and van Heusden S. Mechanism of glass darkening by a low pressure mercury discharge J. Eleclrochem. Soc. 130(2) 440-449 (1983)
80.
Sykes D E., Walls J M. and Raffle J F. Secondary ion mass spectrometry: a materials diagnostic technique for the lighting industryProc. Third Int. Symp. Sci. Technol. Light Sources, Toulouse, France p 160(April 1983)
81.
Wilhartitz P., Virag A., Friedbacher G., Grasserbauer M. and Ortner H.M.Multielement ultratrace analysis in tungsten using secondary ion mass spectrometryFresenius Z. Anal. Chem.329228-236 (1987)
82.
Grasserbauer M., Charalambous P.M., Jakubowski N., Stuewer D., Vieth W., Beske HE, Virag A. and FriedbacherG Ultratrace analysis of refractory metals by solid state mass speCtroscopy-a comparison of GDMS, SSMS and SIMSMikrochim. Acta1291-319 (1987)
83.
Gao L Q. and Li F. Translucent alumina tube used for high pressure sodium lamp Proc. Fourth Int. Symp. Sci. Technol. Light Sources, Karlsruhe, Germany pp271-272 (April 1986)
84.
Garbe S. and Hanloh S. Growth of potassium-filled bubbles in doped tungsten and its relation to hot spot development and intergranular fracture P roc. Third Int. Symp. Sci. Technol. Light Sources, Toulouse , France pp139-140 (April 1983)
85.
Kock A J H M.The surface structure of translucent alumina, a scanning electron microscopy investigationProc. Electrochem. Soc. ed. Zubler E G 88(4) 194-205 (1988)
86.
Hodge J D. Alkaline earth effects on the reaction of sodium with aluminum oxide Proc. Electrochem. Soc. ed. Zubler E G 85(2) 261-270 (1985)
87.
Datta R K. Calcia enhanced β-Al2O3 formation in high-pressure sodium discharge lampsProc . Electrochem. Soc. ed. Zubler E G 85(2) 271-290 (1985)
88.
Craig R F.The scanning electron microscope as a diagnostic tool for high pressure sodium lampsProc. Third Int. Symp. Sci. Technol Light Sources, Toulouse, France pp158-159 (April 1983)
89.
Vrugt P J. Compatibility of alumina (sapphire) and sodium in the temperature range of 1075-1525K Proc. Electrochem. Soc. ed. Zubler E G 85(2) 237-250 (1985)
90.
Tiernan R J. and Shinn D B. Sodium reactions with high pressure sodium arc tube alumina Proc. Electrochem. Soc. ed. Zubler E G 85(2) 251-260 (1985)
91.
van Erk W. and Rietveld T.The transport of silicon and silica in rare earth metal halide lampsProc. Electrochem. Soc. ed. Zubler E G 85(2) pp 57-71 (1985)
92.
Snellgrove R A. Seal reactions at high temperatures in discharge lamps Proc. Electrochem. Soc. ed. Zubler E G 88(4) 251-263 (1988)
93.
Wendlandt W W.Thermal Analysis3rd edn. in Chemical Analysis Vol. 19 ed. Elving P J and Winefordner J D (New York: Wiley) (1986)
94.
Speros D M. Physical chemistry of light sources: certain principles and problems Proc. Third Int. Symp. Sci. Technol. Light Sources , Toulouse, France pp30-35 (April 1983)
95.
Nagel F. Factors influencing the quality of Al-Ca-Sr-Y oxide seals for HPS lampsProc. Electrochem. Soc. ed Zubler E G 88(4) 240-250 (1988)
96.
Oomen J J C. and Rouwendal J W. High pressure sodium lamp seals based on rare earth aluminates Proc. Electrochem. Soc. ed. Zubler E G 85(2) 291-312 (1985)
97.
Slavin W.Flames, furnaces, plasmas, how do we choose? Anal. Chem. 58(4) 589A-597A ( 1986)
98.
de Galan L.New directions in optical atomic spectroscopyAnal. Chem. 58(6) 697A-707A ( 1986)
99.
Slavin W AtomicAbsorption Spectroscopy in Chemical Analysis Vol. 25 ed. Elving P J and Kolthoff I M (New York: Interscience) (1968)
100.
Meyer G A.ICP—still the panacea for trace metals analysis? Anal. Chem. 59(23) 1345A-1354A (1987)
101.
Moore G.L.Introduction to Inductively Coupled Plasma Atomic Emission Spectrometry (New York: Elsevier) ( 1989)
102.
Boumans P W J M.Inductively Coupled Plasma Emission Spectroscopy Parts 1 and 2 in Chemical Analysis Vol. 90 ed. Elving P J and Winefordner J D (New York: Wiley ) (1987)
103.
Pribil R. and Vesely V.Contributions to the basic problems of coInplcxometry-XVI: determination of thorium and scandium in the presence of each otherT alanta111545-1548 (1964)
104.
Schwarzenbach G. and Flaschka H.Complexometric Titrations 2nd English edition (London: Methuen) ( 1969)
105.
Solleveld G D A. Chemical analysis of sodium, mercury, aluminum and trace elements in high pressure sodium lamps P roc. Fifth Int. Symp. Sci. Technol. Light Sources, York , England pp123-124 (September 1989)
106.
Harrison W W., Hess K R., Marcus R K. and King F L.Glow discharge mass spectrometryAnal. Chem. 58(2) 341A-356A ( 1986)
107.
Ehmann W.D. and Vance D.E.Advances in neutron activation analysis CRC Crit. Rev. Anal. Chem.20(6) 405-443 (1989)
108.
Griffiths P R. and de Haseth J A FourierTransform Infrared Spectrometry in Chemical Analysis Vol. 83 ed. Elving P J and Winefordner J D (New York: Wiley ) ( 1986)
109.
van der Steen G H A M. and Papanikolau E.Introduction and removal of hydroxyl groups in vitreous silicaPhilips Res. Rep. 30(2-5) 103-119, 192-205 and 309-319 (1975)
110.
Shinn D B. Chemical and materials problems affecting lamps P roc. Fifth Int. Symp. Sci. Technol. Light Sources, York , England pp129-138 (September 1989)
111.
Prangle N.M. and Goodman W.F.FTIR in the examination of fused silicaLab. Pract.38(10) 91 ( 1989)
112.
Wetzel R A., Pohl C A., Riviello J M. and Macdonald J C IonChromatography in Inorganic Chromatographic Analysis ed. Macdonald J C in Chemical Analysis Vol. 78 ed Elving P J and Winefordner J D (New York: Wiley) pp 355-416 (1985)
113.
Fritz J S.Ion chromatographyAnal. Chem . 59(4) 335A-344A ( 1987)
114.
Small H.Modern inorganic chromatographyAnal. Chem. 55(2) 235A-242A (1983)
115.
Brumleve T R.Determination of traces of water, hydroxide, and oxide in metal halide salts by coulometric Karl Fischer titrationAnal. Chim. Acta15579-87 (1983)
116.
Wiedijk P.Simultaneous microdetermination of water and oxygen in metal halides by reductive fusion in an inert gasAnal. Chim. Acta81105-110 (1976)
117.
Nargolwalla S S. and Przybylowicz E P.Activation Analysis with Neutron Generators in Chemical Analysis Vol. 39 ed. Elving P J and Kolthoff I M (New York: Wiley) (1973)
118.
Waymouth J F., Koury F., Gungle W C. and Peterson C. Sodium loss processes in metal iodide arc lamps Illum. Engr. 62(4) 214-220 (1967)
119.
Nagel F. and Kaposi O. On the ionic mechanism of sodium loss in metal-halogen lamps Proc. Electrochem. Soc. ed. Zubler E G 85-272-77 (1985)
120.
Nagel F., Szanto J., Adam J. and Peter I.Sodium loss in NaI containing metal-halide lampsProc. Fourth Int. Conf. Sci. Technol. Light Sources, Karlsruhe , Germany pp97-98 (April 1986)
121.
Nagel F. The ionic mechanism of sodium loss in MH lampsProc. Electrochem. Soc. ed. Zubler E G 88(4) 18-21 (1988)
122.
Keeffe W M. and Meyer V D. Measurement of sodium loss from fused silica metal halide arc tubes Proc. Fifth Int. Symp. Sci. Technol. Light Sources , York, England pp117-118 (September 1989)
123.
Rhodes W H., Dugger D L. and Feuersanger A E. The kinetics and consequences of alkali permeation through HPS envelopesProc. Third Int. Symp. Sci. Technol. Light Sources, Toulouse, France pp 70-71 (April 1983 )
124.
Weinmuller K. Sodium loss in HPS lamps and its investigation by radiochemical methodsProc. Fourth Int. Symp. Sci. Technol. Light Sources, Karlsruhe, Germany pp243-244 (April 1986)