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Abstract

Electric vehicle lithium-ion batteries experience severe transient thermal loads during real-world driving, where elevated temperatures and cell-to-cell nonuniformity accelerate aging and can precipitate thermal runaway. This study proposes a sustainable, passive battery thermal management system based on a nano-enhanced bio-based phase change material (NE-BBPCM) from paraffin wax, walnut shell biochar, and reduced graphene oxide (rGO). rGO was incorporated at 0.1, 0.3, 0.5, and 1.0 wt% via probe ultrasonication, and the composite was microencapsulated to mitigate leakage. DSC and microscopy confirmed preserved phase change behavior and a conductive filler network, while thermophysical testing showed a conductivity rise from 0.25 to 1.5-1.85 W/m·K with latent heat retained at 2.5-220 kJ/kg. Increasing rGO reduced the melt time from 1850 s to 1580 s, increased the maximum temperature suppression from 8.4°C to 12.8°C, shortened the recovery time from 620 s to 530 s, and improved cycling stability to 490 cycles. A3S2P Samsung 18650 module with a 2 mm PCM layers was tested under WLTP and UDDS profiles using thermocouples and IR thermography and was simulated in ANSYS fluent and a UDF heat generation model. Model validation yielded RSME of 1.51°C (WLTP peak), 1.32°C (UDDS peak), and 1.16°C (WLTP PCM average), within the estimated ±1.9°C experimental uncertainty. With rGO PCM, cell temperature decreased from 57.8–58.6°C to 53.7–54.2°C, WLTP/UDSS peak reduction reached 4.4/3.6°C, and cooling time from 55°C to °C dropped from 840 to 545 s (11.4Wh saved) under high speed 35°C ambient, NE-BBPCM reduced peak temperature from 62.4°C to 56.7°C. Overall, NE-BBPCM enables a robust, validated, and scalable passive battery thermal management system for EV duty cycles with improved uniformity and safety.

Keywords

NE-BB PCM lithium-ion battery thermal management rGO composites WLTP simulation phase change materials

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References

Shen

. The control of lithium-ion batteries and supercapacitors in hybrid energy storage systems for electric vehicles: a review. Int J Energy Res 2021; 45: 20524–20544. https://doi.org/10.1002/er.7150

Dubarry

Liaw

. Identify capacity fading mechanism in a commercial LiFePO4 cell. J Power Sources 2009; 194(1): 541–549. https://doi.org/10.1016/j.jpowsour.2009.05.036

Jaguemont

Boulon

Dubé

. A comprehensive review of lithium-ion batteries used in hybrid and electric vehicles at cold temperatures. Appl Energy 2016; 164: 99–114. https://doi.org/10.1016/j.apenergy.2015.11.034

Peng

Chen

Garg

, et al. A review of the estimation and heating methods for lithium-ion batteries pack at the cold environment. Energy Sci Eng 2019; 7: 645–662. https://doi.org/10.1002/ese3.279

Zhang

Luo

, et al. A review on thermal management of lithium-ion batteries for electric vehicles. Energy 2022; 238: 121652. https://doi.org/10.1016/j.energy.2021.121652

Akinlabi

AAH

Solyali

. Configuration, design, and optimization of air-cooled battery thermal management system for electric vehicles: a review. Renew Sustain Energy Rev 2020; 125: 109815. https://doi.org/10.1016/j.rser.2020.109815

Hwang

Confrey

Reidy

, et al. Review of battery thermal management systems in electric vehicles. Renew Sustain Energy Rev 2024; 192: 114171. https://doi.org/10.1016/j.rser.2023.114171

Rao

Wang

Huang

. Investigation of the thermal performance of phase change material/mini-channel coupled battery thermal management system. Appl Energy 2016; 164: 659–669. https://doi.org/10.1016/j.apenergy.2015.12.021

Peng

Wang

Jiang

. Numerical study of PCM thermal behavior of a novel PCM-heat pipe combined system for Li-ion battery thermal management. Appl Therm Eng 2022; 209: 118293. https://doi.org/10.1016/j.applthermaleng.2022.118293

10.

Wang

Guo

Ren

, et al. Investigation of the thermal management potential of phase change material for lithium-ion battery. Appl Therm Eng 2024; 236: 121590. https://doi.org/10.1016/j.applthermaleng.2023.121590

11.

Talluri

Kim

Shin

. Analysis of a battery pack with a phase change material for the extreme temperature conditions of an electrical vehicle. Energies 2020; 13(3): 507. https://doi.org/10.3390/en13030507

12.

Hayatina

Auckaili

Farid

. Review on the life cycle assessment of thermal energy storage used in building applications. Energies 2023; 16: 1170. https://doi.org/10.3390/en16031170

13.

Smaisim

Sajadi

, et al. Impact of phase change material-based heatsinks on lithium-ion battery thermal management: a comprehensive review. J Energy Storage 2022; 52: 104874.

14.

Wang

Cheng

Jin

, et al. Review on bio-based shape-stable phase change materials for thermal energy storage and utilization. J Renew Sustain Energy 2022; 14: 052701. https://doi.org/10.1063/5.0102005

15.

Jilte

Kumar

. Thermal performance of a novel confined flow Li-ion battery module. Appl Therm Eng 2019; 146: 1–11. https://doi.org/10.1016/j.applthermaleng.2018.09.099

16.

Mahamud

Park

. Reciprocating air flow for Li-ion battery thermal management to improve temperature uniformity. J Power Sources 2011; 196(13): 5685–5696. https://doi.org/10.1016/j.jpowsour.2011.02.076

17.

Spitthoff

Shearing

Burheim

. Temperature, ageing and thermal management of lithium-ion batteries. Energies 2021; 14: 1248.

18.

Zhao

Wang

Negnevitsky

, et al. A review of air-cooling battery thermal management systems for electric and hybrid electric vehicles. J Power Sources 2021; 501: 230001. https://doi.org/10.1016/j.jpowsour.2021.230001

19.

Sharma

Prabhakar

. A review on air cooled and air centric hybrid thermal management techniques for Li-ion battery packs in electric vehicles. J Energy Storage 2021; 41: 102885. https://doi.org/10.1016/j.est.2021.102885

20.

Liu

Weng

, et al. Phase change materials application in battery thermal management system: a review. Materials 2020; 13: 4622. https://doi.org/10.3390/ma13204622

21.

Kumar Thakur

Sathyamurthy

Velraj

, et al. A state-of-the art review on advancing battery thermal management systems for fast-charging. Appl Therm Eng 2023; 226: 120303. https://doi.org/10.1016/j.applthermaleng.2023.120303

22.

Afzal

Abdul Razak

Mohammed Samee

, et al. A critical review on renewable battery thermal management system using heat pipes. J Therm Anal Calorimetry 2023; 148: 8403–8442.

23.

Zhang

Tavakoli

Abidi

, et al. Investigation of horizontal and vertical distance of lithium-ion batteries on the thermal management of the battery pack filled with phase change material with the air flow. J Power Sources 2022; 550: 550.

24.

Arshad

Jabbal

Yan

. Preparation and characteristics evaluation of mono and hybrid nano-enhanced phase change materials (NePCMs) for thermal management of microelectronics. Energy Convers Manag 2020; 205: 112444. https://doi.org/10.1016/j.enconman.2019.112444

25.

Kumar

Mitra

Srinivas

. Role of nano-additives in the thermal management of lithium-ion batteries: a review. J Energy Storage 2022; 48: 104059. https://doi.org/10.1016/j.est.2022.104059

26.

Ghalkhani

Habibi

. Review of the Li-Ion battery, thermal management, and AI-Based battery management system for EV application. Energies 2023; 16: 185. https://doi.org/10.3390/en16010185

27.

Astaneh

Andric

Löfdahl

, et al. Multiphysics simulation optimization framework for lithium-ion battery pack design for electric vehicle applications. Energy 2022; 239: 122092. https://doi.org/10.1016/j.energy.2021.122092

28.

Vikram

Vashisht

Rakshit

. Performance analysis of liquid-based battery thermal management system for electric vehicles during discharge under drive cycles. J Energy Storage 2022; 55: 105737. https://doi.org/10.1016/j.est.2022.105737

29.

Kadam

Kongi

. Battery thermal management system based on PCM with addition of nanoparticles. In: Materials Today: Proceedings, 2023.

30.

Zhu

Xiong

Chen

, et al. Thermal analysis and optimization of an EV battery pack for real applications. Int J Heat Mass Tran 2020; 163: 120384. https://doi.org/10.1016/j.ijheatmasstransfer.2020.120384

31.

Chan

Chung

Raman

. Optimizing thermal management system in electric vehicle battery packs for sustainable transportation. Sustainability 2023; 15(15): 11822. https://doi.org/10.3390/su151511822

32.

Cicconi

Landi

Germani

. Thermal analysis and simulation of a Li-ion battery pack for a lightweight commercial EV. Appl Energy 2017; 192: 159–177. https://doi.org/10.1016/j.apenergy.2017.02.008

33.

Amiribavandpour

Shen

, et al. An improved theoretical electrochemical-thermal modelling of lithium-ion battery packs in electric vehicles. J Power Sources 2015; 284: 328–338. https://doi.org/10.1016/j.jpowsour.2015.03.022

34.

Kant

Pitchumani

. Analysis and design of battery thermal management under extreme fast charging and discharging. J Energy Storage 2023; 60: 106501. https://doi.org/10.1016/j.est.2022.106501

35.

Safira

Putra

Trisnadewi

, et al. Thermal properties of sonicated graphene in coconut oil as a phase change material for energy storage in building applications. Int J Low Carbon Technol 2020; 15(4): 629–636. https://doi.org/10.1093/ijlct/ctaa018

Thermal testing of battery packs with nano-enhanced bio-based phase change materials in EVs under driving cycles

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