In order to achieve accurate state of charge (SOC) estimation of Lithium-Ion Battery, A method that dual Extended Kalman filters (DEKF) optimized by PSO-based Gray Wolf optimizer (MGWO) is proposed. A second-order equivalent circuit model with two resistor-capacitor branches is applied. The battery parameters are determined by battery test. Dual Extended Kalman filters are divided into state filter and parameter filter. Parameter filter is applied to adjust battery parameters online, state filter is applied to SOC estimation. Meanwhile, MGWO is applied to optimize the noise covariance matrix to improve the state estimation accuracy of SOC which reduces the linearization error from EKF. The results shows that the accuracy of algorithm is improved by adding online parameter identification and the optimization of the noise covariance matrix, meanwhile, the proposed method can adapt to the initial error well.
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