Abstract
A series of new polyimides were synthesized by condensation of pyridine-bridged novel diamine monomers, bis(4-aminobenzoyloxy-3,5-dimethyl phenyl)-3′-pyridyl methane and 2,6-bis(2-amino-3-pyridyloxy)pyridine, with various aromatic anhydrides. The monomers and precursors were characterized by elemental analysis, Fourier transform infrared (FTIR), proton nuclear magnetic resonance (1H NMR), and carbon-13 nuclear magnetic resonance (13C NMR) spectroscopic techniques. The structure of the polymers were characterized by FTIR and 1H-NMR spectroscopy, and the physical properties of the polymers, including the glass transition temperature (in the range of 199–319°C), thermal and thermo-oxidative stability (10% weight loss temperature is in the range of 375–539°C in air and 403–542°C in nitrogen atmospheres), the char yield in the range of 37.91–56.65% at 800°C, solubility, solution viscosity (0.81–1.81), molecular weight data, optical properties, crystallinity, mechanical properties like tensile strength (86–102 MPa), elongation at break (12.5–16.5%), tensile modulus (1.2–1.8 GPa), and moisture absorption were also studied.
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