Development and characterization of novel organic–inorganic hybrid sol–gel films

Abstract

Organic–inorganic hybrid films were fabricated by reacting 3-glycidoxypropyltrimethoxysilane with 4,4′-diaminodiphenylether by hydrolysis and condensation reaction with acid catalysis. The chemical bonding between the organic and inorganic phases provides reinforcement to the films, and tetraethoxysilane was added in such a way that silica contents varied from 1 wt% to 3 wt% in the films. Structural characterization of the hybrid films was performed using Fourier transform infrared and nuclear magnetic resonance spectroscopic techniques. The thermal properties studied using thermogravimetric analysis, indicate an improved thermal stability for the films according to the percentage concentration of silica present in them. The water absorption was also found to be reduced for the films with increased silica content. The surface morphology was investigated by means of x-ray diffraction and scanning electron microscopic techniques. The films transparency and homogeneity seem to have been affected severely when the silica content kept on increasing and ultimately led to opaqueness in film.