Talc added to PA-6 fire retardant with APP increases the oxygen index and upgrades the UL94 ranking to class V0. A chemical reaction of APP with talc, detected in the mixtures above 350°C, prevents volatilization of poly phosphoric acid and increases the amount of thermally stable solid residue. The inorganic phosphates that are formed improve the insulating properties of the intumescent layer on the surface of burning PA-6, as compared to the use of APP alone.
Kopylov, B.B., S.N. Novikov and L.A. Oksent'evich .1986. Polymeric Materials with Low Flammability. Moscow: Khimiya (in Russian).
2.
Pearce, E.M., S.W. Shalaby and R.H. Barker.1975. Flame-Retardant Polymeric Materials , Vol. 1, M. Lewin , S. M. Atlas and E. M. Pearce, eds., New York: Plenum Press, pp. 239-290.
3.
Camino, G., M.P. Luda and L. Costa.1993. "Chemical Industry and Environment ," Proceedings of the European Meeting on Chemical Industry and Environment , Vol. 1, Catalonia, June 2-4, pp. 221-225.
4.
Levchik, S.V., G. Camino, L. Costa and G. Levchik.Fire and Materials (to be published).
5.
Levchik, S.V. , L. Costa and G. Camino.1992. Poly. Deg. and Stab ., 36:229-237.
6.
Levchik, S.V. , L. Costa and G. Camino.1993. Makromol. Chem., Macromol. Symp., 74:95-99.
Levchik, S.V. , G.F. Levchik, A.F. Selevich, G. Camino and L. Costa.1993. Proceedings of the 2nd Beijing International Symposium/Exhibition of Flame Retardants , Beijing, October 11-15, pp. 197-202.
11.
Camino, G., L. Costa and L. Trosarelli.1985. Poly. Deg. and Stab., 12:203-211.
12.
Levchik, G.F. , A.F. Selevich, S.V. Levchik and A.I. Lesnikovich.Thermochim. Acta (to be published).
13.
Thomas, L.C.1974. Interpretation of the Infrared Spectra of Organophosphorus Compounds. London: Heyden.