Abstract
This work reports hygroscopic, thermal, and mechanical properties of biomass composites comprising sisal fiber reinforcing castor oil PU resin. The effects of reinforcement geometry and alkaline treatment of fibers were evaluated. In general, alkaline treatment improved quasi-static tensile properties of composites with short randomly oriented and long aligned sisal fibers, respectively. On the other hand, an adverse effect of alkaline treatment was observed in the mechanical behavior of the composite with bidirectional fabric architecture. The outstanding influence of moisture on thermo-mechanical properties of biomass composites was confirmed through thermogravimetric and differential scanning calorimetry techniques. Dynamical-mechanical thermal analysis showed increased storage modulus (i.e., stiffness) and decreased damping properties of biomass composites as compared to neat PU matrix. Dynamical-mechanical testing also detected unexpected decrease on glass transition temperature of composites in regard to the neat polymer resin; resin plasticization due to moisturized fibers and/or alkaline treatment residues was identified as probably the culprit.
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