A study was made of the addition of a copolymer of ethylene with vinyl acetate (CEVA) on the cracking resistance of a composite based on high-density polyethylene (HDPE) and linear low-density polyethylene (LLDPE). It was shown that the introduction into the composite of a small quantity (0.5–1.5 wt%) of CEVA of certain composition in the form of its concentrate based on LLDPE leads to a significant increase in the stress cracking resistance of the composite, with retention of high physicomechanical properties.
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References
1.
ArkhipovaZ.V., High-density Polyethylene: Scientific and Technical Principles of Industrial Synthesis.Khimiya, Leningrad, 240 pp. (1980).
2.
HowardJ.B., Stress cracking, in Structural Properties of Plastics (Physicochemical Principles of Application) (trans. from English), ed. by BaerE.Khimiya, Moscow, pp. 331–378 (1967).
3.
GOST 16338-85, High-density polyethylene. Specifications.Izd-vo Standartov, Moscow, 54 pp. (1987).
4.
BaulinA.A., The production and properties of chromocene catalyst for the synthesis of high-density polyethylene by the gas-phase method, in Catalysts and Initiators for the Production of Polymerisation Plastics. Collection of Scientific Proceedings.ONPO Plastpolimer, Leningrad, pp. 80–89 (1987).
5.
PolyakovA.V. (ed.), Polyolefins. Catalogue.ONPO Plastpolimer, Leningrad, 36 pp. (1990).
6.
BaulinA.A., The production of low-density polyethylene by the low-pressure method. Plast. Massy, (10): 17–18 (1981).
7.
VeselovskayaE.V., Copolymers of Ethylene.Khimiya, Leningrad, 224 pp. (1983).
8.
BaulinA.A., The production of a catalyst for the synthesis of HDPE by the gas-phase method. Plast. Massy, (8): 7–9 (1985).
9.
ZelentsovV.V., The synthesis of linear low-and medium-density polyethylene by the gas-phase method. Plast. Massy, (2): 50–51 (1991).
10.
BaulinA.A., A highly effective applied chromium oxide catalyst for the production of high-density polyethylene in the gas-phase copolymerisation of ethylene with butene-1. Vys. Soed., 50 (12): 2082–2089 (2008).
11.
BaulinA.A., Catalysts for the synthesis of LLDPE by the gas-phase polymerisation method (review). Plast. Massy, (3): 6–8 (1985).
12.
BaulinA.A., and BobrovB.N., The development and application of effective catalysts for the gas-phase (co)polymerisation of ethylene – the basis for renewing the grade range of HDPE produced by OAO Kazan'orgsintez. Proc. Sci.-Pract. Conf. – Polymerisation Plastics, Production and Processing - 2008, OAO Plastpolimer, St Petersburg, pp. 49–52 (2009).
13.
SakhabutdinovA.G., Modern universal gas-phase technology for producing ‘Sferilen’ polyethylene. Proc. Anniv. Sci.-Pract. Conf. – Urgent Questions and Prospects of Development of OAO Kazan'orgsintez, OAO Kazan'orgsintez, Kazan, pp. 24–25 (2013).
14.
PlokhotskiA., Blends of polyolefins: rheology, melt blending, and application, in Polymer Blends, ed. by PaulD., and NewmanS.Academic Press, New York, NY (1978).
15.
WilsonD.R., Polymer molding compositions. US Patent 7790826, Appl. No. 11/121353, filed 3 May 2005; patent date 7 September 2010.
16.
Neidinger W.K., Melt blended polyethylene–ethylene copolymer polyblends. US Patent 3784668, Appl. No. 43591, filed 4 June 1970; patent date 8 January 1974.
17.
ZaikinA.E., and NigmatullinV.A., The influence of the nature of distribution of the filler on the deformation properties of blends of polyethylene with copolymers of ethylene with vinyl acetate. Zh. Prikl. Khim., 69 (8):1359–1362 (1996).
18.
GordienkoV.P., Radiation Modification of Composite Materials Based on Polyolefins.Naukova Dumka, Kiev, 176 pp. (1985).
19.
BaulinA.A., Method for producing stabilised composites based on high-density polyethylene with increased cracking resistance. Russian Patent 2471821, No. 2011123074/04, appl. 08.06.11, publ. 10.01.13. Byull., (1), 23 pp.
20.
SirotaA.G., and BugorkovaV.S., The effectiveness of polar modifying additives to polyethylene. Plast. Massy, (5): 6–11 (2010).