Superabsorbent hydrogels, polystyrene-graft-polyacrylic acid (PAA; PS-g-PAA), linear low-density polyethylene (LLDPE)-graft-PAA (LLDPE-g-PAA), and hydrogel composites, PS-g-PAA/bentonite (BT), were synthesized through emulsion polymerization using acrylic acid as a monomer, benzoyl peroxide as an oil-soluble initiator, and ammonium persulfate and sodium sulfite as a redox initiator in the presence of N,N-methylenebisacrylamide as a cross-linking agent. The superabsorbents were characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, and scanning electron microscopy. The maximum water absorbencies for PS-g-PAA and PS-g-PAA/BT were 780 and 900 g g−1 in distilled water, respectively, while the water absorbency of LLDPE-g-PAA superabsorbent was 450 g g−1 in distilled water.
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