Abstract
A study has been made of the effects of copper oxinate and nickel oxinate on the actinic degradation of cotton fabric. Both compounds were found to be protective at all concentrations studied, and their behavior is considered to relate to the fact that they are stable metal chelates and not ionic salts, which are known to accelerate the degradation of cotton. Furthermore, both compounds were found to absorb light in the high-energy ultraviolet region. The results are discussed in terms of structure and degree of ultra violet absorption of the compounds.
Get full access to this article
View all access options for this article.
References
1.
Bayley. C.H.
,
Rose, G.R.F.
,
Clifford. J.B.
, and
Cooney. J.D.
, Textile Res. J.
33 , 849 -554 (1963 ).
2.
Beelik, A.
and
Hamilton, J.K.
, Papier
13 , 77 -85 (1959 ).
3.
Chaudet, J.H.
,
Newland, G.C.
,
Patton. H.W.
, and
Tamblyn, J.W.
, SPE Trans.
1 , 26 -30 (1961 ).
4.
Egerton, C.S.
, "The Mechanism of the Photochemical Degradation of Textile Materials," The Society of Dyers and Colourists , "Symposium on Photochemistry in Relation to Textiles ," Harrogate , 1949 .
5.
Flynn, J.H.
,
Wilson, W.K.
, and
Morrow, W.L.
, J. Res. Natl. Bur. Std.
60 , 239 -233 (1958 ).
6.
Gingras, B.A.
,
Cooney, J.D.
,
Jackson. K.A.
, and
Bailey, C.H.
Textile Res. J.
33 , 1000 -1004 (1963 ).
7.
Heuser, E.
and
Chamberlin, C.N.
J. Am. Chem. Soc.
68 , 79 -83 (1946 ).
8.
Hollingshead, R.G.W.
, "Oxine and its Derivatives, Part I ." London , Butterworths Scientific Publications , 1954 , p. 12 .
9.
Rose, G.R.F.
and
Bayley, C.H.
, Textile Res. J.
24 , 792 -802 (1954 ).
10.
Rose, G.R.F.
,
Clifford, J.B.
, and
Bayley. C.H.
, Textile Res. J.
31 , 1 -14 (1961 ).
11.
Scientific Oil Compounding Co. Inc., U. S. Patents 2.561.379 and 2.561.380 (1951); U. S. Patent 2,769,006 (1956).
12.
Scientific Oil Compounding Co, Inc., U. S. Patent 2,772,261 (1956).
13.
Snell, F.D.
and
Snell. C.T.
, "Colorimetric Methods of Analysis ," Vol. 11, 3 rd Edition. New York , D. Van Nostrand Company, Inc. , 1949 , pp. 345 -347 .
14.
Stilling, R.A.
and
Van Nostrand, R.I.
, J. Am. Chem. Soc.
66 , 753 -760 (1944 ).