The effects of conductive polymers on conductivities and morphologies of electrospun fabrics are analyzed. The factors that affect the conductivities and morphologies are discussed. Some applications of these conductive nanofibers are reported. The introduction of conductive polymers into nanofiber mats has the potential to provide sufficient conductivity for many applications. An improved conductivity can be achieved by maximizing the content of conjugated polymers. The selection of conductive and carrier polymers, solvents, doping agents, oxidizing agents and ratios of them are also important to obtain sufficient properties. Carbon fiber, carbon black and carbon nanotubes are not covered in this review.
BozdagKDChiouNRPrigodinaVN. Magnetic field, temperature and electric field dependence of magneto-transport for polyaniline nanofiber networks. Synth Met2010; 160: 271–274.
6.
NayakRPadhyeRKyratzisIL. Recent advances in nanofibre fabrication techniques. Textil Res J2012; 82: 129–147.
7.
HeJHKongHYYangRR. Review on fiber morphology obtained by bubble electrospinning and blown bubble spinning. Therm Sci2012; 16: 1263–1279.
8.
VazquezBVasquezHLozanoK. Preparation and characterization of polyvinylidene fluoride nanofibrous membranes by forcespinning. Polym Eng Sci2012; 10: 2260–2265.
9.
CavaliereSSubiantoSSavychI. Electrospinning: designed architectures for energy conversion and storage devices. Energy Environ Sci2011; 4: 4761–4785.
10.
SubbiahTBhatGSTockRW. Electrospinning of nanofibers. J Appl Polym Sci2005; 96: 557–569.
11.
SalemDR. Structure formation in polymeric fibers, electrospinning and the formation of nanofibers by Fong, H, Reneker, DH, Hanser Publishers, 2001, pp. 226–237.
12.
JianFTaoNHTongL. Applications of electrospun nanofibers. Chinese Sci Bull2008; 5: 2265–2286.
13.
YanilmazMKalaoğluFKarakaşH. Study on optimising the morphology of electrospun polyurethane nanofibers. Textil Apparel2012; 3: 212–217.
14.
MiaoJMiyauchiMSimmonsTR. Electrospinning of nanomaterials and applications in electronic components and devices. J Nanosci Nanotechnol2010; 10: 5507–5519.
15.
LiXHaoXYuH. Fabrication of polyacrylonitrile/polypyrrole (PAN/PPy) composite nanofibres and nanospheres with core–shell structures by electrospinning. Mater Lett2008; 62: 1155–1158.
16.
DemirMMYılgörIYılgörE. Electrospinning of polyurethane fibres. Polymer2002; 43, 11: 3303–3309.
17.
YanilmazMKalaogluFKarakasH. Investigation on the effect of process variables on polyurethane nanofibre diameter using a factorial design. Fibres Textil East Eur2013; 98: 19–21.
HuangZMZhangYZKotakicM. A review on polymer nanofibers by electrospinning and their applications in nanocomposites. Compos Sci Technol2003; 63: 2223–2253.
20.
SilvaABBretasRES. Preparation and characterization of PA6/PANI-TSA nanofibers. Synth Met2012; 162: 1537–1545.
21.
BajiAMaiYWWongSC. Electrospinning of polymer nanofibers: effects on oriented morphology, structures and tensile properties. Compos Sci Technol2010; 70: 703–718.
LiuXChenJGilmoreKJ. Guidance of neurite outgrowth on aligned electrospun polypyrrole/poly(styrene-b-isobutylene-b-styrene) fiber platforms. J Biomed Mater Res A2010; 94: 1004–1011.
25.
ShirikawaHLouisEJMacDiarmidAG. Synthesis of electrically conducting organic polymers Halogen derivatives of polyacetylene. Chem Sot Chem1977; 474: 578–580.
AdelojuSBWallaceGG. Conducting polymers and the bioanalytical sciences: new tools for biomolecular communications: a review. Analyst1996; I21: 699–703.
34.
SadikOA. Bioaffinity sensors based on conducting polymers: a short review. Electroanalysis1999; 11: 839–844.
35.
RahmanaNANikolaidisaMGRayaS. Functional electrospun nanofibres of poly(lactic acid) blends with polyaniline or poly(aniline-co-benzoic acid). Synth Met2010; 160: 2015–2022.
36.
LongYZLiMMGuC. Recent advances in synthesis, physical properties and applications of conducting polymer nanotubes and nanofibers. Prog Polym Sci2011; 36: 1415–1442.
37.
HongKHKangTJ. Polyaniline–nylon 6 composite nanowires prepared by emulsion polymerization and electrospinning process. J Appl Polym Sci2006; 99: 1277–1286.
38.
SujithKAshaAMAnjaliP. Fabrication of highly porous conducting PANI-C composite fiber mats via electrospinning. Mater Lett2012; 67: 376–378.
YanılmazMErbayBTSerhatliE. Synthesis of urethane acrylate based electromagnetic interference shielding materials. J Appl Polym Sci2013; 127: 4957–4966.
44.
SenSDavisFJMitchellGR. Conducting nanofibres produced by electrospinning. J Phys Conf Ser2009; 183: 012020–012020.
45.
HanGShiG. Novel route to pure and composite fibers of polypyrrole. J Appl Polym Sci2007; 103: 1490–1494.
46.
XieJMacEwanMRWillerthSM. Conductive core–sheath nanofibers and their potential application in neural tissue engineering. Adv Funct Mater2009; 19: 2312–2318.
47.
NairSHsiaoEKimSH. Fabrication of electrically-conducting nonwoven porous mats of polystyrene–polypyrrole core–shell nanofibers via electrospinning and vapor phase polymerization. J Mater Chem2008; 18: 5155–5161.
48.
JuYWParkJHJungHR. Electrochemical properties of polypyrrole/sulfonted SEBS composite nanofibers prepared by electrospinning. Electrochim Acta2007; 52: 4841–4847.
49.
CetinerSKalaogluFKarakasH. Electrospun nanofibers of polypyrrole-poly(acrylonitrile-co-vinyl acetate). Textil Res J2010; 80: 1784–1792.
50.
KaiDPrabhakaranMPJinG. Polypyrrole-contained electrospun conductive nanofibrous membranes for cardiac tissue engineering. J Biomed Mater Res A2011; 99: 376–385.
51.
YanilmazMKalaogluFKarakasH. Preparation and characterization of electrospun polyurethane–polypyrrole nanofibers and films. J Appl Polym Sci2012; 125: 4100–4108.
52.
RahyAYangDJ. Synthesis of highly conductive polyaniline nanofibers. Mater Lett2008; 62: 4311–4314.
53.
YuQZShiMMDengM. Morphology and conductivity of polyaniline sub-micron fibers prepared by electrospinning. Mater Sci Eng B2008; 150: 70–76.
54.
CardenasJRFrancaMGOVasconcelosEA. Growth of sub-micron fibres of purepolyaniline using the electrospinning technique. J Phys D Appl Phys2007; 40: 1068–1071.
55.
YuXLiYZhuN. A polyaniline nanofibre electrode and its application in a self-powered photoelectrochromic cell. Nanotechnology2007; 18: 015201–015201.
56.
KangTJKimDNHongKH. Preparation and properties of polyaniline electrospun fiber web. J Appl Polym Sci2012; 12: 4033–4037.
57.
ChoiSSChuBYHwangDS. Preparation and characterization of polyaniline nanofiber webs by template reaction with electrospun silica nanofibers. Thin Solid Films2005; 477: 233–239.
FryczkowskiaRKowalczykT. Nanofibres from polyaniline/polyhydroxybutyrate blends. Synth Met2009; 159: 2266–2268.
60.
NeubertaSPliszkaaDThavasiaV. Conductive electrospun PANI-PEO/TiO2 fibrous membrane for photo catalysis. Mater Sci Eng2011; 176: 640–646.
61.
HongKHOhKWKangTJ. Preparation of conducting nylon-6 electrospun fiberwebs by the in situ polymerization of polyaniline. J Appl Polym Sci2005; 96: 983–991.
62.
LaforgueARobitailleL. Fabrication of poly-3-hexylthiophene/polyethylene oxide nanofibers using electrospinning. Synth Met2008; 158: 577–584.
DingBLiCMiyauchiY. Formation of novel 2D polymer nanowebs via electrospinning. Nanotechnology2006; 17: 3685–3691.
66.
PantHRRisalPParkCH. Core–shell structured electrospun biomimetic composite nanofibers of calcium lactate/nylon-6 for tissue engineering. Chem Eng J2013; 221: 90–98.
67.
PantHRNamKTOhHJ. Effect of polymer molecular weight on the fiber morphology of electrospun mats. J Colloid Interf Sci2011; 364: 107–111.
68.
DongHNyameVMacdiarmidAG. Polyaniline/poly(methyl methacrylate) coaxial fibers: the fabrication and effects of the solution properties on the morphology of electrospun core fibers. J Polym Sci Pol Phys2004; 42: 3934–3942.
69.
HeJH. Allometric scaling law in conductive polymer. Polymer2004; 45: 9067–9070.
70.
PiccianiPHSMedeirosESPanZ. Structural, electrical, mechanical, and thermal properties of electrospun poly(lactic acid)/polyaniline blend fibers. Macromol Mater Eng2010; 29: 618–627.
71.
PiccianiPHSMedeirosESPanZ. Development of conducting polyaniline/poly(lactic acid) nanofibers by electrospinning. J Appl Polym Sci2009; 112: 744–753.
BendreaADCiangaLCiangaI. Review paper: progress in the field of conducting polymers for tissue engineering applications. J Biomater Appl2011; 26: 3–84.
77.
CervantesSARocaMIMartinezJG. Fabrication of conductive electrospun silk fibroin scaffolds by coating with polypyrrole for biomedical applications. Bioelectrochemistry2012; 85: 36–43.
AtesMYilmazKShahryariA. A Study of the electrochemical behavior of poly[N-vinyl carbazole] formed on carbon-fiber microelectrodes and its response to dopamine. IEEE Sensors J2008; 8: 1628–1639.
80.
MacagnanoAZampettiEPantaleiS. Nanofibrous PANI-based conductive polymers for trace gas analysis. Thin Solid Films2011; 520: 978–985.
HaynesABGoumaP. Electrospun polyaniline composites for NO2 detection. Mater Manuf Process2007; 22: 764–767.
83.
JiSLiYYangM. Gas sensing properties of a composite composed of electrospun poly(methyl methacrylate) nanofibers and in situ polymerized polyaniline. Sensor Actuator B2008; 133: 644–649.
84.
JiLYaoYToprakciO. Fabrication of carbon nanofiber-driven electrodes from electrospun polyacrylonitrile/polypyrrole bicomponents for high-performance rechargeable lithium-ion batteries. J Power Sources2010; 195: 2050–2056.
