Nanocomposite based on polypropylene and octadecylamine-modified lamellar-zirconium phosphate (PP/nano-ZrPOct) was prepared by melt processing. The action of the nanofiller and screw speed on the properties were evaluated. SEM images revealed that at highest screw speed, the higher nano-ZrPOct dispersion was achieved. In WAXD diffractrograms, some nanofiller diffraction peaks disappeared and a new peak was observed at low angle. There was evidence of increase of thermal stability although only discrete increasing in initial degradation temperature has been noticed. Melting and crystallization temperatures were invariable but crystallinity degree was influenced with a decreasing behavior at highest screw speed. The results strongly evidenced that the intercalation of the PP chains inside the nano-ZrPOct galleries and some degree of delamination of the nanofiller platelets have been achieved.
BritoGFOliveiraADDAraújoEMet al.Nanocompósitos de polietileno/argila bentonita nacional: influência da argila e do agente compatibilizante PE-g-MA nas propriedades mecânicas e de inflamabilidade. Polímeros2008; 18: 170–177.
LiuSYingJZhouXet al.Dispersion, thermal and mechanical properties of polypropylene/magnesium hydroxide nanocomposites compatibilized by SEBS-g-MA. Compos Sci Technol2009; 69: 1873–1879.
4.
KhosrokhavarRNaderiGBakhshandehGRet al.Effect of processing parameters on PP/EPDM/Organoclay nanocomposites using Tagushi analisys method. Iran Polym J2011; 20: 41–53.
5.
KontouEENiaounakisM. Thermo-mechanical properties of LLDPE/SiO2 nanocomposites. Polymer2006; 47: 1267–1280.
6.
BalowMJGlobal Trends of Polypropylene. In: KarianHG (ed). Handbook of polypropylene and polypropylene composites, 2nd ed. New York: Madison, 2003, pp. 1–9.
7.
CardosWSGushikemY. Preparação de compostos lamelares: síntese do hidrogenofosfato de zircônio cristalino e sua intercalação com aminas. Um experimento para estudantes de graduação. Quím Nova2005; 28: 723–726.
8.
Dal PontKGérardJFEspucheE. Modification of α-ZrP nanofillers by amines of different chain length: consequences on the morphology and mechanical properties of styrene butadiene rubber based nanocomposites. Eur Polym J2012; 48: 217–227.
9.
MaJLiuCLiRet al.Preparation and properties of castor oil-based polyurethane/α-zirconium phosphate composite films. J Appl Polym Sci2011; 121: 1815–1822.
10.
WangDYLiuXQWangJSet al.Preparation and characterisation of a novel fire retardant PET/α-zirconium phosphate nanocomposite. Polym Degrad Stab2009; 94: 544–549.
11.
NunesLMAiroldiC. Hidrogenofosfato de titânio lamelar: síntese, troca iônica e intercalação. Quim Nova2001; 24: 799–807.
12.
VelascoJIArdanuyMRealinhoVet al.Polypropylene/clay nanocomposites: combined effects of clay treatment and compatibilizer polymers on the structure and properties. J Appl Polym Sci2006; 102: 1213–1223.
13.
CostantinoAPettarinVVianaJet al.Polypropylene/clay nanocomposites produced by shear controlled orientation in injection moulding: deformation and fracture properties. Strojniški vestnik – J Mech Eng2013; 59: 697–704.
14.
Arada PérezMLALandazury YanesSCardonaMet al.CopperII-selective electrodes based on 1-furoyl-3,3-diethylthiourea as a neutral carrier. J Chil Chem Soc2010; 55: 371–373.
15.
AtaeefardMMoradianS. Polypropylene/organoclay nanocomposites: effects of clay content on properties. Polym Plast Technol Eng Polym2011; 50: 732–739.
16.
LertwimolnunWVergnesB. Influence of compatibilizer and processing conditions on the dispersion of nanoclay in a polypropylene matrix. Polymer2005; 46: 3462–3471.
17.
BarbosaRMoraisDDSNóbregaKCet al.Influence of processing variables on the mechanical behavior of HDPE/clay nanocomposites. Mater Res2012; 15: 477–482.
18.
MendesLCSilvaDFAraujoLJFet al.Zirconium phosphate organically intercalated/exfoliated with long chain amine. J Therm Anal Calorim2014; 118: 1461–1469.
19.
BrandãoLSMendesLCMedeirosMEet al.Thermal and mechanical properties of poly(ethylene terephthalate)/lamellar zirconium phosphate nanocomposites. J Appl Polym Sci2006; 102: 3868–3876.
20.
MendesLCSilvaDFLinoAS. Linear low-density polyethylene and zirconium phosphate nanocomposites: evidence from thermal, thermo-mechanical, morphological and low-field nuclear magnetic resonance techniques. J Nanosci Nanotechnol2012; 12: 8867–8873.
21.
KalantariBMojtahediMRMShoushtariAMet al.Effect of hot drawing process on physical and thermal properties of polypropylene fiber containing selective peroxide and comparison with conventional polypropylene fibers. Polímeros2012; 22: 467–474.
22.
ModestiMLorenzettiABonDet al.Effect of processing conditions on morphology and mechanical properties of compatibilized polypropylene nanocomposites. Polymer2005; 46: 10237–10245.
23.
DomenechTPeuvrel-DisdierEVergnesB. Influence of twin-screw processing conditions on structure and properties of polypropylene – organoclay nanocomposites. Int Polym Proc2012; 27: 517–526.
24.
Silverstein RM, Bassler GC and Morril TC. Spectrometric identification of organic compounds. 6th ed. New York: John Wiley & Sons, Inc., 1998, p.482.
25.
LongoCSavarisMZeniMet al.Degradation study of polypropylene (PP) and bioriented polypropylene (BOPP) in the environment. Mater Res2011; 14: 442–448.
26.
PainterPCWatzekMKoenigJL. Fourier transform infra-red study of polypropylene. Polymer1977; 18: 1169–1172.
27.
SakaharaRLimaAWangSH. Influence of the beta crystalline phase fraction on the mechanical behavior of polypropylene/calcium carbonate/polypropylene–graft–maleic anhydride composites. Polímeros2014; 24: 554–560.
28.
LinoASMendesLCSilvaDFet al.High density polyethylene and zirconium phosphate nanocomposites. Polímeros2015; 25: 477–482.
29.
AkbariBBagheriR. Influence of compatibilizer and processing conditions on morphology, mechanical properties, and deformation mechanism of PP/Clay nanocomposite. J Nanomater2012; 2012: 1–8.
30.
DomenechTPeuvrel-DisdierEVergnesB. The importance of specific mechanical energy during twin screw extrusion of organoclay based polypropylene nanocomposites. Compos Sci Technol2013; 75: 7–14.
31.
DomenechTPeuvrel-DisdierEVergnesB. Influence of twin-screw processing conditions on structure and properties of polypropylene – organoclay nanocomposites. Int Polym Proc2012; 27: 517–526.
32.
SantosKSDemoriRMaulerRSet al.The influence of screw configurations and feed mode on the dispersion of organoclay on PP. Polím Ciên Tecnol2013; 23: 175–181.
33.
ModestiMLorenzettiABonDet al.Thermal behaviour of compatibilised polypropylene nanocomposite: effect of processing conditions. Polym Degrad Stab2006; 91: 672–680.
34.
FuadMYAHanimHZarinaRet al.Polypropylene/calcium carbonate nanocomposites – effects of processing techniques and maleated polypropylene compatibiliser. eXPRESS Polym Lett2010; 4: 611–620.
35.
WangJWangCRunM. Study on morphology, rheology, and mechanical properties of Poly(trimethylene terephthalate)/CaCO 3 nanocomposites. Int J PolymSci2013; 2013: 1–8.
