Abstract
Studies have been undertaken to investigate the thermodynamic aspects of the reduction roasting of saprolite ores in the Caron Process. Reduction experiments have been conducted in controlled oxygen partial pressure conditions at selected temperatures. Detailed microstructure characterisation and thermodynamic analysis of reduced ore samples, focusing on the phase transformations, nickel recoveries and Ni-Fe alloy compositions produced, were carried out. Comparison has been made between the experimental results and FactSage thermodynamic predictions for these conditions. The differences between between the experimental and predicted results are discussed. It has been shown that the system below 700°C is approximated thermodynamically by considering the nickel–iron alloy product to be in chemical equilibrium with a metastable amorphous oxide phase.
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