Modified carbon black,CB/MnO 2 and CB/MnO 2 /PPy nanocomposites synthesised by microwave-assisted method for energy storage devices with high electrochemical performances
Restricted accessResearch articleFirst published online October, 2020
Modified carbon black,CB/MnO 2 and CB/MnO 2 /PPy nanocomposites synthesised by microwave-assisted method for energy storage devices with high electrochemical performances
In this study, binary (CB/MnO2) and ternary nanocomposites (CB/MnO2/PPy) include carbon black (CB) and manganese (IV) oxide (MnO2) and polypyrrole (PPy) were chemically synthesized and were characterized by many techniques such as: FTIR-ATR, Raman spectroscopy, SEM-EDX, TGA-DTA analysis, XRD, TEM and BET surface analysis. Electroactive materials were used as a symmetric supercapacitor device system and taken 3 methods (cyclic voltammetry (CV), galvanostatic charge/discharge (GCD), and electrochemical impedance spectroscopy (EIS)). CB/MnO2/PPy nanocomposite at [CB]o/[MnO2]o/[Py]o = 1:1:3 showed a highest specific capacitance of Csp = 273.2%F/g at a scan rate of 1 mV/s in 1 M H2SO4 solution. This nanocomposite combination supplies higher energy and power densities of supercapacitor device (E = 0.5513 Wh/kg and P = 91.556 W/kg at 6 mV/s). Equivalent circuit model of Rs(C1(R1(C2(R2W)))) was used to analyze circuit parameters. Furthermore, the symmetric device for CB/MnO2/PPy nanocomposite at [CB]o/[MnO2]o/[Py]o = 1:1:5 shows an excellent long cycle life with 92.20% of initial capacitance retention after 1000 cycles. CB/MnO2/PPy nanocomposite electrode can be a candidate for supercapacitor applications.
LiuL, NiuZ, ChenJ.Design and integration of flexible planar micro-supercapacitors. Nano Res. 2017; 10: 1524–1544. doi: 10.1007/s12274-017-1448-z
4.
ZhangJ, JiangJ, LiH, A high performance asymmetric supercapacitor fabricated with graphene based electrodes. Energy Environ Sci. 2011; 4: 4009–4015. doi: 10.1039/c1ee01354h
5.
LiuC, LiF, MaLP, Advanced materials for energy storage. Adv Mater. 2010; 22: E28–E62. doi: 10.1002/adma.200903328
PrasadKR, MiuraN.Electrochemically synthesized MnO2-based mixed oxides for high performance redox supercapacitors. Electrochem Commun. 2004; 6: 1004–1008. doi: 10.1016/j.elecom.2004.07.017
13.
ChenJ, WangY, CaoJ.Flexible and solid-state asymmetric supercapacitor based on ternary graphene/MnO2/carbon black hybrid film with high power performance. Electrochim Acta. 2015; 182: 861–870. doi: 10.1016/j.electacta.2015.10.015
14.
WuYQ, XuZ, YaoA, Supercapacitors based on flexible graphene / polyaniline nanofiber composite films. ACS Nano. 2010; 4: 1963–1970. doi: 10.1021/nn1000035
WangGX, ZhangBL, YuZL, Manganese oxide/MWNYs composite electrodes for supercapacitors. Solid State Ion. 2005; 176: 1169–1174. doi: 10.1016/j.ssi.2005.02.005
20.
NarayananA, MugeleF, DuitsMGH.Mechanical history dependence in carbon black suspensions for flow batteries: a Rheo-impedance study. Langmuir. 2017; 33 ( 7 ): 1629–1638. doi: 10.1021/acs.langmuir.6b04322
21.
BadotJC, LestriezB, Dubrun fautO.Interest in broad band dielectric spectroscopy to study the electronic transport in materials for lithium batteries. Mater Sci Eng B. 2016; 213: 190–198. doi: 10.1016/j.mseb.2016.05.012
22.
ZhangY, NarayananA, MugeleF, Charge inversion and colloidal stability of carbon black in battery electrolyte solutions. Colloids Surf A Physicochem Eng Asp. 2016; 489: 461–468. doi: 10.1016/j.colsurfa.2015.08.041
23.
CrouchE, CowellDC, HaskinsS, A novel disposable, screen-printed amperometric biosensor for glucose in serum fabricated using a water-based carbon ink. Biosens Bioelectron. 2005; 21: 712–718. doi: 10.1016/j.bios.2005.01.003
24.
ZhaD, XiongP, WangX.Strongly coupled manganese ferrite / carbon black / polyaniline hybrid for low-cost supercapacitors with high rate capability. Eelectrochim Acta. 2015; 185: 218–228. doi: 10.1016/j.electacta.2015.10.139
25.
YangLW, GaoZ, WangJ, Synthesis of reduced graphene nanosheet / urchin-like manganese dioxide composite and high performance as supercapacitor electrode. Electrochim Acta. 2012; 69: 112–119. doi: 10.1016/j.electacta.2012.02.081
26.
WangGP, ZhangL, ZhangJJ.A review of electrode materials for electrochemical supercapacitors. Chem Soc Rev. 2012; 41: 797–828. doi: 10.1039/C1CS15060J
ChangZ, ZhuX, JuX, Synthesis of hierarchical hollow urchin-like HGRs/MoS2/MnO2 composite and its excellent supercapacitor performance. J Alloys Compd. 2019; 775: 241–247. doi: 10.1016/j.jallcom.2018.10.166
29.
XuB, YuL, SunM, One-pot hydrothermal synthesis of novel 3D starfish-like-δ-MnO2 nanosheets on carbon fiber paper for high-performance supercapacitors. RSC Adv. 2017; 7: 14910–14916. doi: 10.1039/C7RA00787F
30.
BaileyMR, DonneSW.The effect of barium hydroxide on the rechargeable performance of alkaline δ-MnO2. J Electrochem Soc. 2012; 159: A999–A1004. doi: 10.1149/2.047207jes
31.
ChaiY, LiZ, WangJ, Construction of hierarchical holey graphene/MnO2 composites as potential electrode materials for supercapacitors. J Alloys Compd. 2019; 775: 1206–1212. doi: 10.1016/j.jallcom.2018.10.259
32.
WangSI, SunarsoJ, WangBT, Towards enhanced energy density of graphene based supercapacitors: current status, approaches, and future directions. J Power Sources. 2018; 396: 182–206. doi: 10.1016/j.jpowsour.2018.06.004
33.
ZhangX, WangJ, LiuJ, Design and preparation of a ternary composite of graphene oxide/carbon dots/polyprrole for supercapacitor application: importance and unique role of carbon dots. Carbon N Y. 2017; 115: 134–146. doi: 10.1016/j.carbon.2017.01.005
ZhangX, ZhangJ, ChenY, Freestanding 3D polypyrrole @ reduced graphene oxide hydrogels as binder-free electrode materials for flexible asymmetric supercapacitors. J Colloid Interface Sci. 2019; 536: 291–299. doi: 10.1016/j.jcis.2018.10.044
37.
XuQ, WeiC, ShiW, Characterization of doped polypyrrole / manganese dioxide nanocomposite for supercapacitor electrodes. Mater Chem Phys. 2011; 131: 529–534. doi: 10.1016/j.matchemphys.2011.10.016
38.
PurkaitT, SinghG, KambojN, All-porous heterostructure of reduced graphene oxide-polypyrrole-nanoporous gold for a planar flexible supercapacitor showing outstanding volumetric capacitance and energy density. J Mater Chem A. 2018; 6: 22858–22869. doi: 10.1039/C8TA07627H
39.
JenczykJ, BudychMW, JancelewiczM, Structural and dynamic study of block copolymer-nanoparticles nanocomposites. Polymer. 2019; 167: 130–137. doi: 10.1016/j.polymer.2019.01.080
40.
RamanI, ChandrasekaranNI, PugazhendhiA, Investigation of photoelectrochemical activity of cobalt tin sulfide synthesized via microwave-assisted and solvothermal process. J Alloys Compd. 2019; 778: 496–506. doi: 10.1016/j.jallcom.2018.10.403
41.
MuB, ZhangWB, ShaoSJ, Glycol assisted synthesis of graphene-MnO2-polyaniline ternary composites for high performance supercapacitor electrodes. Phys Chem Chem Phys. 2014; 16: 7872–7880. doi: 10.1039/c4cp00280f
42.
WuQH, ChenM, WangSS, Preparation of sandwich-like ternary hierarchical nanosheets manganese dioxide/polyaniline/reduced graphene oxide as electrode material for supercapacitor. Chem Eng J. 2016; 304: 29–38. doi: 10.1016/j.cej.2016.06.060
43.
AbdalMAAM, EdrisNMMA, KulandaivaluS, Supercapacitor with superior electrochemical properties derived from symmetrical manganese oxide-carbon fiber coated with polypyrrole. Int J Hyd Ener. 2018; 43: 17328–17337. doi: 10.1016/j.ijhydene.2018.07.093
ChenY, XuJH, YangYJ, The preparation and electrochemical properties of PEDOT:PSS/MnO2/PEDOT ternary film and its application in flexible microsupercapacitor. Electrochim Acta. 2016; 193: 199–205. doi: 10.1016/j.electacta.2016.02.021
46.
LinJX, ZhengYY, DuQF, Synthesis and electrochemical properties of graphene / MnO2 / conducting polymer ternary composite for supercapacitors. Nano. 2013; 8 ( 1 ): 1350004–1350012. doi: 10.1142/S1793292013500045
47.
RamadossA, KimSJ.Improved activity of a graphene-TiO2-hybrid electrode in an electrochemical supercapacitor. Carbon N Y. 2013; 63: 434–445. doi: 10.1016/j.carbon.2013.07.006
48.
AcocellaMR, CorcioneCE, GiuriA, Catalytic activity of oxidized carbon black and graphene oxide fort he crosslinking of epoxy resins. Polymers. 2017; 9: 133–148. doi: 10.3390/polym9040133
49.
HanG, LiuY, KanE, Sandwich-structured MnO2/polypyrrole/reduced graphene oxide hybrid composites for high performance supercapacitor. RSC Adv. 2014; 4: 9898–9904. doi: 10.1039/C3RA47764A
50.
Ibáñez-RedinG, SilvaTA, VicentiniFC, Effect of carbon black functionalization on the analytical performance of a tyrosinase biosensor based on glassy carbon electrode modified with dihexadecyl phosphate film. Enzyme Microb Tech. 2018; 116: 41–47. doi: 10.1016/j.enzmictec.2018.05.007
51.
BorahD, SatokawaS, KatoS, Characterization of chemically modified carbon black for sorption application. Appl Surf Sci. 2008; 254: 3049–3056. doi: 10.1016/j.apsusc.2007.10.053
52.
Da SilvaLMG, LemosHG, SantosSF, Polyaniline/carbon black nanocomposites: The role of synthesis conditions on the morphology and properties. Mater Today Commun. 2018; 16: 14–21. doi: 10.1016/j.mtcomm.2018.04.008
53.
BiY, NautiyalA, ZhangH, Facile and ultrafast solid-state microwave approach to MnO2-NW@graphite nanocomposites for supercapacitor. Ceram Int. 2018; 44: 5402–5410. doi: 10.1016/j.ceramint.2017.12.169
54.
KumarN, DineshkumarP, RameshbabuR, Morphological analysis of ultra fine α-MnO2 nanowires under different reaction conditions. Mater Lett. 2015; 158: 309–312. doi: 10.1016/j.matlet.2015.05.172
55.
KumarN, PrasadKG, SenA, Enhanced pseudocapacitance from finely ordered pristine α-MnO2 nanorods favourably high current density using redox additive. Appl Surf Sci. 2018; 449: 492–499. doi: 10.1016/j.apsusc.2018.01.025
56.
ZhiX, ZhouH.Optimizing the preparation conditions of polypyrrole electrodes for enhanced electrochemical capacitive performances. Chem Pap. 2018; 72: 2513–2522. doi: 10.1007/s11696-018-0473-z
DallasP, NiarchosD, VrbanicD, Interfacial polymerization of pyrrole and in situ synthesis of polypyrrole/silver nanocomposites. Polymer. 2007; 48: 2007–2013. doi: 10.1016/j.polymer.2007.01.058
ChiuHY, ChoCP.Mixed-phase MnO2-N-containing graphene composites applied as electrode active materials for flexible asymmetric solid-state supercapacitors. Nanomaterials. 2018; 8: 924–947. doi: 10.3390/nano8110924
61.
LiDJ, LiY, FengYY, Hierarchical graphene oxide / polyaniline nanocomposites prepared by interfacial electrochemical polymerization for flexible solid state supercapacitors. J Mater Chem A. 2015; 3: 2135–2143. doi: 10.1039/C4TA05643D
62.
ChenXN, MengFC, ZhouZW, One-step synthesis of graphene/polyaniline hybrids by in-situ intercalation polymerization and their electromagnetic properties. Nanoscale. 2014; 6: 8140–8148. doi: 10.1039/C4NR01738B
63.
WangH, LiuJ, ChenZ, Synergistic capacitive behavior between polyaniline and carbon black. Electrochim Acta. 2017; 230: 236–244. doi: 10.1016/j.electacta.2017.01.164
64.
MaSB, LeeYH, AhnKY, Spontaneously deposited manganese oxide on acetylene black in an aqueous potassium permanganate solution. J Electrochem Soc. 2006; 153: C27–C32. doi: 10.1149/1.2130570
65.
XiongS, ZhangX, ChuJ, Hydrothermal synthesis of porous sugarcane bagasse carbon/MnO2 nanocomposite for supercapacitor application. J Electron Mater. 2018; 47: 6575–6582. doi: 10.1007/s11664-018-6569-y
66.
KalambatePK, DarRA, KamaSP, High performance supercapacitor based on graphene-silver nanoparticles-polypyrrole nanocomposite coated on glassy carbon electrode. J Power Sources. 2015; 276: 262–270. doi: 10.1016/j.jpowsour.2014.11.130
67.
WuW, YangL, ChenS, Core-shell nanospherical polypyrrole/graphene oxide composites for high performance supercapacitors. RSC Adv. 2015; 5: 91645–91653. doi: 10.1039/C5RA17036B
68.
BeshanatSF, ManteghianM, AbdollahiM.Study of polypyrrole / graphene oxide nanocomposite structural and morphological changes including porosity. Polymer Sci Series: B. 2018; 60: 664–674. doi: 10.1134/S1560090418050032
69.
Nguyen-ThanhD, FrenkelAI, WangJ, Cobalt-polypyrrole-carbon black (Co-PPy-CB) electrocatalysts for the oxygen reduction reaction (ORR) in fuel cells: composition and kinetic activity. Appl Catal B. 2011; 105: 50–60. doi: 10.1016/j.apcatb.2011.03.034
70.
HovY, ChengY, HobsonT, Design and synthesis of hierarchical MnO2 nanospheres/carbon nanotubes/conducting polymer ternary composite for high performance electrochemical electrodes. Nano Lett. 2010; 10: 2727–2733. doi: 10.1021/nl101723g
71.
WangB, QiuJ, FengH, Preparation of graphene oxide/polypyrrole/multi-walled carbon nanotube composite and its application in supercapacitors. Electrochim Acta. 2015; 151: 230–239. doi: 10.1016/j.electacta.2014.10.153
72.
ZhengZ, ZhouH, LongX, Electrodeposition of hierarchical manganese oxide on metal nanoparticles decorated nanoporous gold with emhanced supercapacitor performence. J Alloys Compd. 2015; 632: 376–385. doi: 10.1016/j.jallcom.2015.01.240
SinguBS, YoonKR.Synthesis and characterization of MnO2-decorated graphene for supercapacitors. Electrochim Acta. 2017; 231: 749–758. doi: 10.1016/j.electacta.2017.01.182
75.
NathBC, MohanKJ, BaruaR, Dimensionally integrated a-MnO2/carbon black binary complex as platinum free counter electrode for dye sensitized solar cell. J Photochem Photobiol A. 2017; 348: 33–40. doi: 10.1016/j.jphotochem.2017.06.041
76.
DonnetJB, BansalRC, WangMJ.Carbon black science and technology. 2nd ed. New York (NY ): Marcel Dekker; 1993.
77.
BeckF, DolataM, GriveiE, Electrochemical supercapacitor based on industrial carbon blocks in aqueous H2SO4. J Appl Electrochem. 2001; 31: 845–853. doi: 10.1023/A:1017529920916
78.
LiuWW, YanX, LangJ, Flexible and conductive composite electrode based on graphene nanosheets and cotton cloth for supercapacitor. J Mater Chem. 2012; 22: 17245–17253. doi: 10.1039/c2jm32659k
79.
AsenP, ShahrokhianS.A high performance supercapacitor based on graphene/ polypyrrole/Cu2O-Cu(OH)2 ternary nanocomposite coated on nickel foam. J Phys Chem C. 2017; 121: 6508–6519. doi: 10.1021/acs.jpcc.7b00534
80.
DhibarS, DasCK.Silver nanoparticles decorated polyaniline / multiwalled carbon nanotubes nanocomposite for high performance supercapacitor electrode. Ind Eng Chem Res. 2014; 53: 3495–3508. doi: 10.1021/ie402161e
81.
YanJ, LiuJ, FanZ, High performance supercapacitor electrodes based on highly corrugated graphene sheets. Carbon N Y. 2012; 50: 2179–2188. doi: 10.1016/j.carbon.2012.01.028
82.
ViswanathanA, ShettyAN.Facile in-situ single step chemical synthesis of reduced graphene oxide-copper oxide-polyaniline nanocomposite and its electrochemical performance for supercapacitor application. Electrochim Acta. 2017; 257: 483–493. doi: 10.1016/j.electacta.2017.10.099
83.
SarkerAK, HongJD.Electrochemical reduction of ultrathin graphene oxide / polyaniline films for supercapacitor electrodes with a high specific capacitance. Colloids Surf A Physicochem Eng Aspects. 2013; 436: 967–974. doi: 10.1016/j.colsurfa.2013.08.043
84.
ChenYL, HuZA, ChangYQ, Zinc oxide/reduced graphene oxide composites and electrochemical capacitance enhanced by homogeneous incorporation of reduced graphene oxide sheets in zinc oxide matrix. J Phys Chem C. 2011; 115: 2563–2571. doi: 10.1021/jp109597n
85.
WuZS, LiuZ, ParvezK, Ultrathin pritable graphene supercapacitors with AC line-filtering performance. Adv Mater. 2015; 27: 3669–3675. doi: 10.1002/adma.201501208
86.
ChenY, ZhangJ, LiM, Strong interface coupling and few-crystalline MnO2/reduced graphene oxide composites for supercapacitors with high cycle stability. Electrochim Acta. 2018; 292: 115–124. doi: 10.1016/j.electacta.2018.09.131
87.
YangL, WeiW, XiaJ, Electrochemical studies of derivatized thiol self-assembled monolayers on gold electrode in the presence of surfactants. Anal Sci. 2005; 21: 679–684. doi: 10.2116/analsci.21.679
88.
ShayehJS, SadeghiniaM, SiadatSOR, A novel route for electrosynthesis of CuCr2O4 nanocomposite with p-type conductive polymer as a high performance material for electrochemical supercapacitors. J Colloid Interface Sci. 2017; 496: 401–406. doi: 10.1016/j.jcis.2017.02.010
89.
EhsaniA, MahjaniMG, HosseiniM, Evaluation of Thymus vulgaris plant extract as an eco-friendly corrosion inhibitor for stainless steel 304 in acidic solution by means of electrochemical impedance spectroscopy, electrochemical noise analysis and density functional theory. J Colloid Interface Sci. 2017; 490: 444–451. doi: 10.1016/j.jcis.2016.11.048
90.
EhsaniA, BigdelooM, AnsariMY, Nanocomposite of conjugated polymer / nanoflowers Cu(II) metal-organic system with 2-methylpyridine carboxaldehyde isonicotinohydrazide as a novel and hybrid electrode material for highly capacitive pseudocapacitors. Bull Chem Soc Jpn. 2018; 91: 617–622. doi: 10.1246/bcsj.20170391
91.
TabernaPL, SimonP, FauvarqueJF.Electrochemical characteristics and impedance spectroscopy studies of carbon-carbon supercapacitors. J Electrochem Soc. 2003; 150: A292–A300. doi: 10.1149/1.1543948
92.
ShiriHM, EhsaniA, KhalesMJ, Electrochemical synthesis of Sm2O3 nanoparticles: Application in conductive polymer composite films for supercapacors. J Colloid Interface Sci. 2017; 505: 940–946. doi: 10.1016/j.jcis.2017.06.086
93.
AdjariFB, KowsariE, EhsaniA, New synthesized ionic liquid functionalized graphene oxide: synthesis, characterization and its nanocomposite with conjugated polymer as effective electrode materials in an energy storage device. Electrochim Acta. 2018; 292: 789–804. doi: 10.1016/j.electacta.2018.09.177
94.
AjdariFB, KowsariE, EhsaniA.Ternary nanocomposites of conductive polymer / functionalized GO / MOFs: synthesis, characterization and electrochemical performance as effective electrode materials in pseudocapacitors. J Solid State Chem. 2018; 265: 155–166. doi: 10.1016/j.jssc.2018.05.038
95.
NaseriM, FotouhiL, EhsaniA, Novel electroactive nanocomposite of POAP for highly efficient energy storage and electrocatalyst: electrosynthesis and electrochemical performance. J Colloid Interface Sci. 2016; 484: 308–313. doi: 10.1016/j.jcis.2016.08.071
