In the present work, we have synthesized sulfone-bridged tetraphenyl porphyrin, 2D
polymer ‘P’
(C44H28N4OySx)n
through a one-pot reaction of tetra(p-bromophenyl) porphyrin, S with sulfur
powder in DMF. The polymer ‘P’ has been further reacted with erythrosine B
for the fabrication of composite photocatalyst, C
(C65H37N4NaOySx)n
using donor– acceptor conjugation protocol. Herein, both compounds (P &
C) have been well characterized by MAS 13C-NMR, XPS, IR, powder
XRD, TGA, SEM-EDX, UV-Vis spectra, and Cyclic Voltammetry. Due to the low HOMO-LUMO band
gap energy, the applicability of the composite photocatalyst (C, 2.1 eV) has
been studied in terms of oxidation of sulfide to sulfoxide. The present work shows a
promising route for the development of sulfone-bridged 2D porphyrin covalent organic
framework (COF) and its composite photocatalyst as well as its usage in photocatalytic
sulfoxidation reaction.
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