In this paper, two novel organic-inorganic hybrid supramolecule compounds {[Cu·L1’·H2O]·(α-Mo8O26)0.5}n1 and compound {[Cu·L2’·H2O]·(α-Mo8O26)0.5}n2 have been synthesized [L1’ = 1, 3-bis (4-carboxylpyridine) propane dibromide, L2’ = 1, 4-bis (4-carboxylpyridine) butane dibromide]. Compounds 1 and 2 have been expressly confirmed by PXRD, IR, X-ray single crystal diffraction and TG. Last, the study found that compounds 1 and 2 have obvious adsorption effects on MB and RhB organic dyes, and compound 2 has high adsorption capacity for MB.
QiaoG.Y., WangF.R., ZhuY., NiuY.Y., A new polyoxometalate supermolecular compound as flfluorescent probe for detecting of Fe (III): Synthesis, structures, and properties, Main Group Chem18(3) (2019), 291–304.
2.
ShuZ.Z., WangC.H., LiY., DuH.J., NiuY.Y., A new Mo/S/Cu polymeric cluster: Synthesis, structure and properties, Main Group Chem15(1) (2015), 67–74.
3.
HuangW.M., LuY.B., XiaoM., WuB.L., YanZ.N., NiuY.Y., Synthesis, structures and applications as flfluorescence probes of novel Hg(II)/Ag(I) functional supramolecular compounds based on nitrogen heterocyclic cations, Main Group Chem17(4) (2018), 273–283.
4.
LiY.Y., XiaoM., NiuY.Y., Three novel cation-induced supramolecular compounds with 1D polymeric lead(II) iodide frameworks: Synthesis and characterization, Main Group Chem17(4) (2018), 257–266.
5.
CroninL., MüllerA., From serendipity to design of polyoxometalates at the nanoscale, aesthetic beauty and applications, Chem Soc Rev41 (2012), 7333–7334.
6.
ShuZ.Z., WangC.H., LiY., DuH.J., NiuY.Y., A new Mo/S/Cu polymeric cluster: Synthesis, structure and properties, Main Group Chem15(1) (2015), 67–74.
7.
DuH.J., ZhangW.L., WangC.H., NiuY.Y., HouH.W., A new nanocrystalline inorganic–organic hybrid exhibiting semiconducting properties and applications, Dalton Trans45 (2016), 2624.
8.
ZhidkovaM.N., AysinaK.E., KotovV.Y., Synthesis and electropolymerization of bis (4-cyano-1-pyridino) alkanes: effect of co- and counter-ions, Electrochimica Acta219 (2016), 673–681.
9.
GadgilB., DmitrievaE., DamlinP., Redox reactions in a linear polyviologen derivative studied by in situ ESR/UV-vis-NIR spectroelectrochemistry, J Solid State Electrochem19 (2015), 77–83.
10.
LiS.B., MaH.Y., PangH.J., Tuning the dimension of POM-based inorganic-organic hybrids from 3D self-penetrating framework to 1D poly-pendant chain via changing POM clusters and introducing secondary spacers, Cryst Eng Comm16 (2014), 2045–2055.
