Abstract
A new supermolecular compound, [C7H10N4][Mo8O26]0.5·H2O has been synthesized from 1,1-bis(imidazole) methane and (NH4)6Mo7O24·4H2O by hydrothermal method. Structural analysis reveals that every asymmetric structure unit of the compound is composed of one [C7H10N4]2+ and half [Mo8O26]4– and one water molecule. Crystal pack of the compound suggests that polyacid anions represent the one-dimensional chain-shaped structure and organic cations parallel the one-dimensional chains. The compound has the characteristics of detection Fe3+, adsorption and catalysis activities.
Get full access to this article
View all access options for this article.
References
1.
(a)
Li
M.X.
Chen
H.L.
Geng
J.P.
He
X.
Shao
M.
Zhu
S.R.
and
Wang
Z.X.
, CrystEngComm 13 (2011 ), 1687 ; (b)
Huang
W.M.
Lu
Y.B.
Xiao
M.
Wu
B.L.
Yan
Z.N.
and
Niu
Y.Y.
, Main Group Chem 17 (2018 ), 273 –283 . (c)
Li
Y.Y.
Xiao
M.
and
Niu
Y.Y.
, Main Group Chem 17 (2018 ), 257 –266 . (d)
Wang
F.R.
Wang
C.H.
Wu
B.L.
Yan
Z.N.
Niu
Y.Y.
and
Hou
Hong-Wei
, Main Group Chem 17 (2018 ), 211 –218 . (e)
Qiao
X.Y.
Li
Z.Y.
Lu
Y.B.
Xiao
M.
Yan
Z.N.
and
Niu
Y.Y.
, Main Group Chem 17 (2 ) (2018 ), 133 –146 . (f)
Lu
Y.Q.
Lu
Y.B.
Wang
F.R.
Huang
W.M.
and
Niu
Y.Y.
, Main Group Chem 17 (1 ) (2018 ), 27 –33 .
2.
(a)
Frey
G.
, J. Solid State Chem 152 (2000 ), 37 . (b)
Rao
C.N.R.
, Proc Indian Acad Sci 113 (2001 ), 363 . (c)
Weler
M.T.
, J Chem Soc Dalton Trans 0 (2000 ), 4227 . (d)
Fujita
M.
Umemoto
K.
Yoshizawa
M.
Fijita
N.
Kusukawa
T.
and
Biradhe
K.
, Chem Commun 0 (2001 ), 509 . (e)
Cotton
F.A.
and
Murillo
C.A.
, Proc Natl Acad Sci 99 (2002 ), 4810 . (f)
Eddaoudi
M.
Kim
J.
Vodak
D.
Sudik
A.
Wachter
J.
O’Keefe
M.
and
Yaghi
O.M.
, Proc Natl Acad Sci 99 (2002 ), 4900 .
3.
Khan
M.I.
, Solid State Chem 152 (2000 ), 105 .
4.
(a)
De Bord
J.R.D.
Haushalter
R.C.
Meyer
L.M.
Rose
D.J.
Zapf
P.J.
and
Zubieta
J.
, Inorg Chim Acta 256 (1997 ), 168 . (b)
Prohopuk
N.
and
Shriver
D.F.
, Inorg Chem 36 (1997 ), 5609 . (c)
Loose
I.
Klein
M.R.
Krebs
B.
Schulz
R.P.
and
Scharbert
B.
, Inorg Chim Acta 263 (1997 ), 99 . (d)
Khan
M.I.
,
Yobenn
G.
and
Doedens
R.J.
, Angew Chem Int Ed Eng l38 (1999 ), 1292 . (e)
Anokhina
E.
Day
C.S.
Essign
M.W.
and
Lachgan
A.
, Angew Chem Int Ed Engl 39 (2000 ), 1047 . (f)
Yan
B.
Xu
Y.
Bu
Y.
Goh
N.K.
Chie
L.S.
and
Stucky
G.D.
, Dalton Trans 13 (2001 ), 2009 . (g)
Schubert
U.
, Chem Mater 13 (2001 ), 3487 . (h)
Xu
B.
Wei
Y.
Barnes
C.L.
and
Peng
Z.
, Systems Angew Chem Int Ed Engl 40 (2001 ), 2290 . (i)
Niu
J.Y.
Wu
Q.
and
Wang
J.P.
, J Chem Soc Dalton Trans 12 (2002 ), 2512 . (k)
Noland
B.K.
Selby
H.D.
Carducci
M.D.
and
Zhang
Z.
, J Am Chem Soc 124 (2002 ), 3222 .
5.
Zang
H.Y.
,
Ke
T.
,
Guan
W.
,
Shun
L.L.
,
Yang
G.S.
,
Shao
K.Z.
,
Yan
L.K.
,
Zhong
M.S.
, Cryst Eng Comm 12 (2010 ), 3684 .
6.
Hagrman
D.
,
Sangregorio
C.
,
O’Connor
C.J.
,
Zubieta
J.
, J Chem Soc Dalton Trans 0 (1998 ), 3707 .
7.
Devi
R.N.
, J Zubieta Inorg Chim Acta 332 (2002 ), 72 .
8.
Xiao
D.R.
,
Hou
Y.
,
Wang
E.B.
Wang
S.T.
and
Hu
C.W.
, Inorg Chim Acta 357 (2004 ), 2525 .
9.
Allis
D.G.
,
Burkholder
E.
,
Zubieta
J.
, Polyhedron 23 (2004 ), 1145 .
10.
Klemperer
W.G.
,
Shum
W.
, J Am Chem Soc 98 (1976 ), 8291 .
11.
Hagrman
D.
,
Zapf
P.J.
,
Zubieta
J.
, Chem Commun 0 (1998 ), 1283 .
12.
Allis
D.G.
,
Raring
R.S.
,
Burkholder
E.
,
Zubieta
J.
, J Mol Struct 688 (2004 ), 11 .
13.
Zhai
Q.G.
,
Lu
C.Z.
,
Zhang
Q.Z.
,
Wu
X.Y.
,
Xu
X.J.
,
Chen
S.M.
,
Chen
L.J.
, Inorg Chim Acta 359 (2006 ), 3875 .
14.
Yue
Z.C.
,
Du
H.J.
,
Li
L.
,
Zhang
W.L.
,
Niu
Y.Y.
, Inorg Chim Acta 410 (2014 ), 136 .
15.
Yue
Z.C.
,
Du
H.J.
,
Niu
Y.Y.
,
Jin
G.X.
, Cryst Eng Comm 15 (2013 ), 9844 .
16.
(a)
Yue
Z.C.
,
Shen
L.X.
,
Wu
H.H.
,
Li
X.H.
,
Niu
Y.Y.
, Cryst Eng Comm 15 (2013 ), 9938 ; (b)
Du
H.J.
Shu
Z.Z.
Niu
Y.Y.
Song
L.S.
and
Zhu
Y.
, J Solid State Chem 190 (2012 ), 296 .
17.
Müller;
A.
,
Beugholt
C.
,
Bud’ko
S.
,
Luban
M.
, Inorg Chem 39 (2000 ), 5176 .
18.
(a)
Zapf
P.J.
Warren
C.J.
Hausalter
R.C.
and
Zubieta
C.
, Chem Commun 2 (1997 ), 154 ; (b)
Debird
J.R.D.
Haushalter
R.C.
and
Meyer
L. Mr
, Inorg Chim Acta 256 (1997 ), 165 ; (c)
Hagrman
D.
Zapf
P.J.
and
Zubieta
, J Chem Commun 0 (1998 ), 1283 .
19.
Fu
Z.X
Lin
J.
Wang
L.
Li
C.
Yan
W.B.
and
Wu
T.
, Cryst Growth Des 16 (2016 ), 2322 .
20.
(a)
Dolomanov
O.V.
Bourhis
L.J.
Gildea
R.J.
Howard
J.A.K.
and
Puschmann
H.
, J OLEX2: Appl Cryst 42 (2009 ), 339 ; (b)
Sheldrick
G.M.
, SHELXTL-97, Program for Crystal Structure Refinement , University of Gottingen , Germany , (1997 ).
21.
Guo
X.Y.
Zhao
F.
Liu
J.J.
Liu
Z.L.
and
Wang
Y.Q.
, J Mater Chem A 5 (2017 ), 20035 .
22.
Zhao
N.
,
Sun
F.X.
,
Zhang
S.X.
,
He
H.M.
,
L
J.
,
Li
Q.
,
Zhu
G.S.
, Inorg Chem 54 (2015 ), 65 .
23.
Ben
J.M
Gelfand
S.
George
K.H.
and
Shi
M.Z.
, Dalton Trans 45 (2016 ), 3668 .
24.
Jin
S.W.
,
Guo
M.
,
Wang
D.Q.
,
Wei
S.S.
,
Zhou
Y.
,
Zhou
Y.P.
,
Gao
X.C.
,
Yun
Z.Y.
, J Molecular Structure 1020 (2012 ), 70 .
25.
Jin
S.W.
,
Guo
M.
,
Wang
D.Q.
,
Cui
H.
, J Molecular Structure 1006 (2011 ), 128 .
26.
Tzeli
D.
,
Petsalakis
I.D.
,
Theodorakopoulos
G.
, Chemical Physics Letters 573 (2013 ), 48 .
27.
Haushalter
R.C.
,
Mundi
A.
, Chem Master 4 (1992 ), 31 .
28.
Yang
C.X.
,
Ren
H.B.
,
Yan
X.P.
, Anal Chem 85 (2013 ), 7441 .
29.
(a)
Sun
X.D.
Yao
S.
Yu
C.Y.
Li
G.H.
Liu
C.M.
Huo
Q.S.
and
Liu
Y.L.
, J Mater Chem A 6 (2018 ), 6363 ; (b)
Chen
D.
Wu
G.H.
Wang
Z.Q.
Ren
W.Z.
Zhang
Y.J.
Shen
Z.Y.
and
Wu
A.G.
, Dalton Trans 45 (2016 ), 8347 ; (c)
Lv
R.
Wang
J.Y.
Zhang
Y.P.
Li
H.
Yang
L.Y.
Liao
S.Y.
Gu
W.
and
Liu
X.
, J Mater Chem A 4 (2016 ), 15494 ; (d)
Liu
J.J.
Ji
G.F.
Xiao
J.N.
and
Liu
Z.L.
, Inorg Chem 56 (2017 ), 4197 .
30.
Xu
L.
,
Li
M.Q.
,
Wang
E.B.
, Mater Lett 54 (2002 ), 303 .
31.
Hu
C.W.
,
Zhang
X.
,
Xu
L.
,
Mu
B.L.
,
Zu
W.
,
Wang
E.B.
, Appl Clay Sci 13 (1998 ), 495 .
32.
Lin
X.
,
Sun
Y.Q.
,
Wang
E.B.
,
Shen
E.H.
,
Liu
Z.R.
,
Hu
C.W.
, J Solid State Chem 146 (1999 ), 533 .
33.
Mccann
M.
,
Maddock
K.
, Polyhedron 14 (1995 ), 2919 .
34.
Xu
L.
,
Sun
Y.Q.
,
Wang
E.B.
,
Shen
E.H.
,
Liu
Z.R.
,
Hu
C.W.
,
Xing
Y.
,
Lin
Y.H.
,
Jia
H.Q.
, Inorg Chem Commun 1 (1998 ), 382 .