Three novel organic–inorganic hybrid supramolecules
{(bcpyp)[Pb2I6]C3H7NO·H2O}n
(1), {(bcpyb)0.5[PbI3]}n(2), and
{(bcpyh)0.5[PbI3]}n (3) have been synthesized by the
self-assembly of lead iodide with 1, 1’-(propane-1,
3-diyl)bis(4-cyanopyridin-1-ium)dibromide (bcpyp·2Br), 1, 1’-(butane-1,
4-diyl)bis(4-cyanopyridin-1-ium)dibromide (bcpyb·2Br) and 1, 1’-(hexane-1,
6-diyl)bis(4-cyanopyridin-1-ium)dibromide (bcpyh·2Br) cationic templates by solvent
evaporation method. X-ray crystallography shows that these compounds are all composed of
pyridine organic dication and halogenated anions, and present new 1D supramolecular chain.
These compounds have been further characterized by IR spectroscopy, UV-Vis spectroscopy
and photocatalysis reaction.
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