Cationic ligand N-methyl-4,4’-bipyridine (MQ) (Scheme 1) reacted respectively with metal halides and pseudohalides to form two organic-inorganic hybrid materials: [MQ][CuI2] (1), [Cu(MQ)(SCN)2] (2), which were characterized by single-crystal X-ray diffraction analyses, infrared spectra (IR), elemental analyses, powder X-ray diffraction (PXRD), and thermogravimetric (TG) analyses. The anion structure of compound 1 is binuclear and 2 is two-dimensional. Compounds 1- 2 show the better characteristic of degradating methylene blue (MB) in water under 500 W Xe vapor lamp irradiation.
HanY., ZhangZ.H., LiuY.Y., NiuY.Y., DingD.G., WuB.L., HouH.W. and FanY.T., External template-assisted self-assembly: Design and synthesis of 4,4′-bipy-Based Mo(W)/Cu/S heterothiometallic polymeric clusters directed by 1,1′-bis(pyridinium)methylene cation, Cryst Growth Des11(8) (2011), 3448.
2.
KitagawaS., KitauraR. and NoroS.I., Functional porous coordination polymers, Angew Chem Int Ed43 (2004), 2334–2375.
3.
NiuY.Y., SongY.L., HouH.H. and ZhuY., Synthesis, structure, and large optical limiting effect of the first coordination polymeric cluster based on an {I@[AgI(inh)]6} hexagram block, Inorg Chem44 (2005), 2553.
4.
XingX.S., SaR.J., LiP.X., ZhangN.N., ZhouZ.Y., LiuB.W., LiuJ., WangM.S. and GuoG.C., Second-order nonlinear optical switching with a record-high contrast for a photochromic and thermochromic bistable crystal, Chem Sci8 (2017), 7751.
5.
LvX.Y., WangM.S., YangC., WangG.E., WangS.H., LinR.G. and GuoG.C., Photochromic Metal Complexes of-Methyl-4,4′-Bipyridinium: Mechanism and Influence of Halogen Atoms, Inorg Chem51 (2012), 4015.
6.
WuX.Y., QiH.X., NingJ.J., WangJ.F., RenZ.G. and LangJ.P., One silver(I)/tetraphosphine coordination polymer showing good catalytic performance in the photodegradation of nitroaromatics in aqueous solution, Appl Catal B168 (2015), 98–104.
7.
DuH., ZhangW., WangC., NiuY. and HouH., A new nanocrystalline inorganic-organic hybrid exhibiting semiconducting properties and applications, Dalton Trans45(6) (2016), 2624.
8.
ShiraziF.S. and AkhbariK., Sonochemical procedures; the main synthetic method for synthesis of coinage metal ion supramolecular polymer nanostructures, Ultrason Sonochem31 (2016), 51–61.
9.
WangC., DuH., LuY., XuM., WuB., NiuY. and HouH., Bis(3,5-lutidine)alkyl dications and their use in the fabrication of organic–inorganic 2d polypseudorotaxane by templated self-assembly, Cryst Growth Des16(5) (2016), 248.
10.
DuH., WangC.,
LiY.,
ZhangW.,
XuM.,
LiS.,
LuY.,
NiuY. and HouH., A supramolecular metal-organic framework derived from bismuth iodide and 4,4 ’-bipyridinium derivative: Synthesis, structure and efficient adsorption of dyes, Micropor Mesopor Mater214 (2015), 136.
11.
NiuY.Y., WuB.L., GuoX.L., SongY.L., LiuX.C., ZhangH.Y., HouH.W., NiuC.Y. and NgS.W., A systematic design and facile construct of metal pseudohalide frameworks directed by 1,ω-bis(pyridinium)alkane cations, Cryst Growth Des8(7) (2008), 2393.
12.
TianS.H., ZhangJ.L., ChenJ., KongL.J., LuJ., DingF.C. and XiongY., Fe2(MoO4)3 as an effective photo-fenton-like catalyst for the degradation of anionic and cationic dyes in a wide pH range, Ind Eng Chem Res52(37) (2013), 13333–13341.
13.
WangF., KeX.H., ZhaoJ.B., et al., Six new metal-organic frameworks with multicarboxylic acids and imidazole based spacers: Syntheses, structures and properties, Dalton Trans40(44) (2011), 11856–11865.
14.
ChenW.T., LiuD.S., YingS.M., ChenH.L. and Xu.Y.P., ZnCl3(4-methyl-4,4’-bipyridinium) with 4-methyl-4,4’ -bipyridinium generated in situ: Synthesis, structure and photoluminescence, Inorg Chem Commun11(10) (2008), 1212–1214.
15.
(a)
DornT.,
JaniakC. and Abu-ShandiK., Hydrogen-bonding, π-stacking and Cl–-anion-pi interactions of linear bipyridinium cations with phosphate, chloride and [CoCl4]2– anions, CrystEngComm7 (2005), 633; (b) P.A. Iyere, W.Y. Boadi and D. Atwood, S. Parkin. Supramolecular aggregation in 4,4′-bipyridin-1,1′-ium dichloride, 4,4′-bipyridin-1,1′-ium dinitrate and 4,4′-bipyridin-1-ium bromide, Acta Crystallogr B59 (2003), 664; (c) L.J. Barbour, L.R. Mac Gillivray and J.L. Atwood, Structural consequences of M-Cl. . . H-N hydrogen bonds in substituted pyridinium salts of the cobalt(II) tetrachloride anion isolated from liquid clathrate media, Supramol Chem7 (1996), 167; (d) A.L. Gillon, G.R. Lewis, A.G. Orpen, S. Rotter, J. Starbuck, X.M. Wang,Y. Rodriguez-Martin and C. Ruiz-Perez, Organic–inorganic hybrid solids: Control of perhalometallate solid state structures, J Chem Soc Dalton Trans0(21) (2000), 3897–3905.
16.
ChenY., WangM.S., CaiL.Z., JiangX.M., WuM.F., GuoG.C. and HuangJ.S., Crystal structures and visible-light excited photoluminescence of N-methyl-4,4′-bipyridinium chloride and its Zn(II) and Cd(II) complexes, Ingon Chem Commun13 (2010), 1021–1024.
17.
CoeB.J., ChamberlainM.C., Essex-LoprestiJ.P., GainesS., JefferyJ.C., HoubrechtsS. and PersoonsA., Large molecular quadratic hyperpolariz abilities in donor/acceptor-substituted-tetraammineruthenium(II) complexes, Inorg Chem36 (1997), 3284–3292.
18.
EmmertB. and StawitzJ., Über die farbe der γ,γ′-dipyridylium-halogenide, Inorg Chem56 (1923), 83–91.
19.
(a)
DolomanovO.V.,
BourhisL.J.,
GildeaR.J.,
HowardJ.A.K. and PuschmannH., J. OLEX2: A complete structure solution, refinement and analysis program, Appl Cryst42 (2009), 339; (b) G.M. Sheldrick, SHELXTL-97, Program for Crystal Structure Refinement, University of Gottingen, Germany, 1997.
20.
CoeB.J., BeyerT., JefferyJ.C., ColesS.J., GelbrichT., HursthouseM.B. and LightM.E., A spectroscopic, electrochemical and structural study of polarizable, dipolar ruthenium(II) arsine complexes as models for chromophores with large quadratic non-linear optical responses, J Chem Soc Dalton Trans0(5) (2000), 797–803.
21.
BerradaM., AnbaouiZ., LajrhedN., BerradaM. and KnouziN., Synthesis, characterization, and studies of heat-resistant poly(ether benzimidazole)s, Chem Mater9 (1997), 1989.
22.
LinL., DengC., LinG.P. and WangY.Z., Super toughened and high heat-resistant poly(lactic acid) (PLA)-based blends by enhancing interfacial bonding and PLA phase crystallization, Ind Eng Chem Res54 (2015), 5643.
23.
LuY.B., WangC.H., DuH.J. and NiuY.Y., Two novel cation-induced supramolecular polymers with 2-3d polymeric cuprous thiocyanate frameworks: Synthesis, characterization and photocatalytic activities for the degradation of organic dye contaminants, Inorg Chim Acta450 (2016), 154.
24.
XuM.M., LiY., ZhengL.J., NiuY.Y. and HouH.W., Three cation-templated Cu(I) self-assemblies: Synthesis, structures, and photocatalytic properties, New J Chem40 (2016), 6086.
