Abstract
The compound [C4H12N2][CoCl4] was ionothermally synthesised in an ionic liquid medium and shown by X-ray single crystal diffraction analysis to consist of four piperazinium C4H12N22+ cations and four CoCl42- complex anions. Thermogravimetric analysis indicated that [C4H12N2][CoCl4] possesses good thermal stability below 320 °C.
References
1.
Shi H.
,
Shan Y.
,
He M.
, and
Liu Y.
, J. Solid State Chem. , 2003 , 176 , 33 .
2.
Stein A.
,
Keller W. S.
, and
Mallou T. E. K.
, Science , 1993 , 259 , 1558 .
3.
Gopalakrishnan T.
, Chem. Mater. , 1995 , 7 , 1265 .
4.
Price G.D.
,
Pluth J. J.
,
Smith J. V.
, and
Araki T.
, Nature , 1981 , 292 , 818 .
5.
Yeganah-haeri A.
,
Weidner D. J.
, and
Parise I. B.
, Science , 1992 , 257 , 650 .
6.
Davies M.E.
, and
Lobo R. F.
, Chem. Mater. , 1992 , 4 , 756 .
7.
Devi R.N.
,
Burkholder E.
, and
Zubieta J.
, Inorg. Chim. Acta , 2003 , 348 , 150 .
8.
Huddleston J.G.
,
Visser A. E.
,
Reichert W. M.
,
Willauer H. D.
,
Broker G. A.
, and
Rogers R. D.
, Green Chem. , 2011 , 3 , 156 .
9.
Wasserscheid P.
, and
Kein W.
, Angew. Chem. Int. Ed. Engl. , 2000 , 39 , 3772 .
10.
Kniep R.
,
Engelhardt H.
, and
Boy I.
, Chem. Mater. , 1998 , 10 , 2930 .
11.
Dumas E.
,
Debiemme-Chouvy C.
, and
Sevov S.
, J. Am. Chem. Soc. , 2002 , 124 , 908 .
12.
Bontchev R.P.
,
Do J.
, and
Jacobson A. J.
, Inorg. Chem. , 2000 , 39 , 3320 .
13.
Kniep R.
,
Will D. H. G.
,
Boy D. I.
, and
Röhr C.
, Angew. Chem. Int. Ed. Engl. , 1997 , 36 , 1013 .
14.
Zhao J.
,
Ma P.
,
Wang J.
, and
Niu J.
, J. Clust. Sci. , 2009 , 4 , 671 .
15.
Liu J.
,
Liu Z.
,
Cheng J.
,
Fang D.
, and
Wang J.
, Chin. J. Inorg. Chem. , 2013 , 2 , 289 .
16.
Tran Qui D.
, and
Palacios E.
, Acta Cryst. C , 1990 , 46 , 1212 .
