Abstract
The complexes {[Mn(L1)(H2O)]2[Pd(CN)4]}·2CH3CN and {[Mn(L2)(H2O)]2[Pd(CN)4]}2·H2O [L1 = N,N-ethylene-bis(5-bromicsalicylideneiminate); L2 = N,N-ethylene-bis(5-methxysalicylideneiminate)] have been obtained from [Pd(CN)4]2- and the corresponding Schiff-base manganese(III) compounds. X-ray diffraction reveals that the complexes are constructed into two-dimensional supramolecular networks through intermolecular O–H…O and O–H…N hydrogen bond interactions. The magnetic susceptibilities of the two complexes reveal overall weak antiferromagnetic interactions between the adjacent Mn(III) ions.
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