Abstract
The complexes [Os3(CO)9(μ3-η2:η2:η2-C70)] and [Re3(μ-H)3(CO)9(μ3-η2:η2:η2-C70)] have been prepared by reaction of C70 with [Os3(CO)10(NCMe)2] or [Re3(μ-H)3(CO)11(NCMe)] and their electrochemical properties studied by cyclic voltammetry in chlorobenzene solutions. The complex [Re3(μ-H)3(CO)8(CNCH2Ph)(μ3-η2:η2:η2-C70)] has also been synthesised by reaction between [Re3(μ-H)3(CO)9(μ3-η2:η2:η2-C70)] and PhCH2N=PPh3.
Keywords
References
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