Abstract
A novel iron porphyrin [FeTCPP] n [TCPP = meso-tetra(4-carboxyphenyl)porphyrin] has been synthesised via a hydrothermal reaction and structurally characterised. It has a two-dimensional structure and is thermally stable up to 320°C. UV–Vis, FT–IR and fluorescence data are also reported. Porphyrins have interesting roles in nature such as in green leaves and red blood cells, as well as applications in medicine, catalysis, optics, conductive materials, magnetism and solar energy conversion.
References
1.
Maeda K.
,
Henbest K.B.
,
Cintolesi F.
,
Kuprov I.
,
Rodgers C.T.
,
Liddell P.A.
,
Gust D.
,
Timmel C.R.
, and
Hore P.J.
, Nature , 2008 , 453 , 387 .
2.
Pan Z.
,
Wang Q.
,
Sheng X.
,
Horner J.H.
, and
Newcomb M.
, J. Am. Chem. Soc. , 2009 , 131 , 2621 .
3.
Drain C.M.
,
Varotto A.
, and
Radivojevic I.
, Chem. Rev. , 2009 , 109 , 1630 .
4.
Bucher C.
,
Devillers C.H.
,
Moutet J.C.
,
Royal G.
, and
Saint-Aman E.
, Coord. Chem. Rev. , 2009 , 253 , 21 .
5.Rigaku (2002) , CrystalClear Version 1.35 , Rigaku Corporation .
6.Siemens (1994 ), SHELXTL™ Version 5 Reference Manual , Siemens Energy & Automation Inc. , Madison, Wisconsin, USA.
7.
Nasri H.
,
Ellison M.K.
,
Haevitz B.
,
Gupta G.P.
, and
Scheidt W.R.
, Inorg. Chem. , 2006 , 45 , 5284 .
8.
Hu C.
,
Noll B.C.
,
Schulz C.E.
, and
Scheidt W.R.
, Inorg. Chem. , 2008 , 47 , 8884 .
9.
Helms A.M.
,
Jones W.D.
, and
McLendon G.L.
, J. Coord. Chem. , 1991 , 23 , 351 .
10.
Chufan E.E.
,
Verani C.N.
,
Puiu S.C.
,
Rentschler E.
,
Schatzschneider U.
,
Incarvito C.
,
Rheingold A.L.
, and
Karlin K.D.
, Inorg. Chem. , 2007 , 46 , 3017 .
11.
Bominaar E.L.
,
Ding X.
,
Gismelseed A.
,
Bill E.
,
Winkler H.
,
Trautwein A.X.
,
Nasri H.
,
Fischer J.
, and
Weiss R.
, Inorg. Chem. , 1992 , 31 , 1845 .
12.
Botar B.
,
Kogerler P.
, and
Hill C.L.
, Inorg. Chem. , 2007 , 46 , 5398 .
13.
Safaei E.
,
Weyhermuller T.
,
Bothe E.
,
Wieghardt K.
, and
Chaudhuri P.
, Eur. J. Inorg. Chem. , 2007 , 2334 .
14.
Albinati A.
,
Calderazzo F.
,
Marchetti F.
,
Mason S.A.
,
Melai B.
,
Pampaloni G.
, and
Rizzato S.
, Inorg. Chem. Commun. , 2007 , 10 , 902 .
15.
Hagrman D.
,
Hagrman P.J.
, and
Zubieta J.
, Angew. Chem., Int. Ed. Engl. , 1999 , 38 , 3165 .
16.
Barron P.M.
,
Son H.T.
,
Hu C.
, and
Choe W.
, Cryst. Growth Des. , 2009 , 9 , 1960 .
17.
Pan L.
,
Kelly S.
,
Huang X.
, and
Li J.
, Chem. Commun. , 2002 , 2334 .
