Abstract
The palladium N-heterocyclic carbene complex trans-[PdCl2{1,3-bis(2,6-diisopropylphenyl)-imidazol-2-ylidene}(NC5H5)] has been prepared and its X-ray molecular structure is reported. The complex is highly catalytically active in the cross-coupling reaction of phenylhalides with phenylthiol to afford diphenyl sulfide and is efficient for the coupling of chlorobenzene.
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