Abstract
Dealumination of the faujasite support was realised using a hydrothermal treatment at different temperatures (625 – 700°C). Then palladium catalysts were prepared by an ion exchange method. The prepared catalysts exhibited a high and constant activity up to 100% for N2O conversion. This performance was dependent on certain parameters, such as a high Si/Al ratio, the structural properties of the zeolitic support, and the metal function provided by the palladium. In addition, it is considered that the active sites in the reaction, which are suspected to be PdO, are influenced by the acidic properties of the support.
Keywords
References
1.La directive 95/2/CE, les additifs alimentaires autres que les colorants, et les édulcorants , (1995 ) Journal Officiel , L 61.
2.
Van den Brink R.W.
,
Booneveld S.
, and
Pels J.R.
(2001 ) Appl. Catal. B , 32 , 63 –71 .
3.
Smeets J.P.
,
Meng Q.
, and
Corthals S.
(2008 ) Appl. Catal. B , 84 , 505 –513 .
4.
Janusz J.
,
Wojciech R.
,
Tetsuya S.
, and
Stanislaw D.
(2012 ) Appl. Catal. B , 123-124 , 134 –140 .
5.
Kameoka S.
,
Kita K.
, and
Takeda T.
(2000 ) Catal. Lett. , 69 , 169 –173 .
6.
Neveu B.
,
Delahay G.
,
Mauvezin M.
, and
Coq B.
(2000 ) Patent WO0048715.
7.
Aika K.
, and
Oshihara K.
(1996 ) Catal. Today , 29 , 123 –126 .
8.
Mauvezin M.
,
Delahay G.
,
Coq B.
, and
Kieger S.
(1999 ) Appl. Catal. B , 23 , L79 –L82 .
9.
Kapteijn F.
,
Rodrigues-Mirasol J.
, and
Moulijn J. A.
(1996 ) Appl. Catal. B , 9 , 25 –64 .
10.
Sun Q.
, and
Sachtler W. M. H.
(2003 ) Appl. Catal. B , 42 , 393 –401 .
11.
Xia H.
,
Sun K.
,
Liu Z.
(2010 ) J. Catal. , 270 , 103 –109 .
12.
Ferreira A.P.
,
Capela S.
,
Da Costa P.
(2007 ) Catal. Today , 119 , 156 –165 .
13.
Pieterse J.A.Z.
,
Van Den Brink R.W.
,
Booneveld S.
, and
De Bruijn F.A.
(2003 ) Appl. Catal. B , 46 , 239 –250 .
14.
Lutz W.
,
Ruscher C.H.
,
Heidemann D.
(2002 ) Microp. Mesop. Mater. , 55 , 193 –202 .
15.
Yan Z.
,
Ma D.
,
Zhuang J.
(2003 ) J. Mol. Catal. A , 194 , 153 –167 .
16.
Gregg S.J.
, and
Sing K.S.W.
(1982 ) Adsorption, surface area and porosity. Academic Press , London , pp. 42 –84 .
17.
Triantafillidis C.S.
,
Vlessidis A.G.
, and
Evmiridis N.P.
(2000 ) Indust. Eng. Chem. Res. , 39 , 307 –319 .
18.
Miessner H.
,
Kosslick H.
,
Lohse U.
,
Parlitz B.
, and
Tuan V.A.
(1993 ) J. Phy. Chem. , 97 , 9741 –9748 .
19.
Zhdmov S.P.
,
Titova T.I.
,
Kosheleva L.S.
, and
Lute W.P.
(1989 ) Appl. Chem. , 61 , 1977 –1998 .
20.
Cundy C.S.
, and
Cox P.A.
(2003 ) Chem. Rev. , 103 , 663 –701 .
21.
Li G.
,
Larsen S.C.
, and
Grassian V.H.
, (2005 ) Catal. Lett. , 103 , 1 –2 .
22.
Corma A.
, (1995 ) Chem. Rev. , 95 , 559 –614 .
23.
Armaroli1 T.
,
Bécue1 T.
, and
Gautier S.
(2004 ) Rev. IFP. , 59 , 215 –237 .
24.
Jacobs P.A.
, and
Uytterhoeven J.B.
(1973 ) J. Chem. Soc., Faraday. Trans. , 69 , 359 –372 .
25.
Lonyi F.
,
Valyon J.
, and
PalBorbely G.
, (2003 ) Microp. Mesop. Mater. , 66 , 273 –282 .
26.
Sazama P.
,
Wichterlova B.
, and
Dedecek J.
(2011 ) Microp. Mesop. Mater. , 143 , 87 –96 .
27.
Sombatchaisak S.
,
Praserthdam P.
,
Chaisuk C.
, and
Panpranot J.
(2004 ) Ind. Eng. Chem. Res. , 43 , 4066 –4072 .
28.
Maeda H.
,
Kinoshita Y.
, and
Reddy K.R.
(1999 ) Appl. Catal. B , 23 , 247 –257 .
29.
Shen W.J.
,
Okumura M.
,
Matsumura Y.
, and
Haruta M.
(2001 ) Appl. Catal. A , 213 , 225 –232 .
30.
Stolz C.
,
Sauvage A.
,
Massiani P.
, and
Kramer R.
(1998 ) Appl. Catal. A , 167 , 113 –121 .
31.
Ogura M.
,
Hayashi M.
,
Kage S.
,
Matsukata M.
, and
Kikuchi E.
(1999 ) Appl. Catal. B , 23 , 247 –257 .
32.
Diaz E.
,
Ordonez S.
,
Vega A.
, and
Coca J.
(2005 ) Appl. Catal. B , 56 , 313 –322 .
