Phenylisothiocyanate reacts with ethyltriphenylphosphanylideneacetate at room temperature to yield 2-(ethoxycar-bonyl)-2-(triphenyl-Λ5-phosphanylidene)-N’-phenylethane thioimidic acid and diethyl-2-(triphenyl-Λ5-phosphanylidene)-3-(phenylimino)pentanedioate. The formation of phosphoranes are explained according to mechanism of the Wittig type reaction. The X-ray analysis structures of phosphorane adducts were studied.
HaruoS., and KeijiT., Yakugaku Zasshi, 1969, 89, 1401.
3.
Alan AitkenR., Al-AwadiN.A., DawsonG., El-DusouqiO.M.E., FarrellD.M.M., KaulK., and KumarA., Tetrahedron, 2005, 61, 129.
4.
HuisgenR., and WulffJ., Tetrahedron Lett., 1967, 10, 917.
5.
OhshiroY., MorjY., MinamiT., and AgawaT., J. Org. Chem., 1970, 3, 2076.
6.
MackayS., GilmoreC.J., EdwardsC., and StewartN., and ShanklandK., maXus Computer Program for the Solution and Refinement of Crystal Structures Bruker Nonius. The Netherlands, MacScience, Japan & The University of Glasgow1999.
7.
JohnsonC.K., PRTEP-II. A Fortran Thermal-Ellipsoid Plot Program. Report ORNL-1976, 5138.Oak Ridge National Laboratory, Oak Ridge, Tennessee, USA.
8.
OtwinowskiZ., and MinorW., Methods in enzymology, Vol. 276, ed. CarterC.W.Jr., R.M. Sweet 1997, Academic Press, New York, pp. 307–325.
9.
AltomareA., CascaranoG., GiacovazzoC., GuagliardiA., BurlaM.C., PolidoriG., and CamalliM., J. Appl. Crystallogr., 1994, 27, 435.
10.
WaasmaierD, and KirfelA., Acta Crystallogr., 1995, A51, 415.
11.
HesseM., MeierH., and Zech;B.Spekhroskopische Methoden in der Organischen Chemie G., Thieme, Stuttgart, 1979.
