Abstract
X-ray crystallography was used to determine the stereo structure of a novel chiral organosilicon compound, (2R)-(–)-(1-cyclohexenyloxy)dimethyl(1-naphthylphenylmethyl) silane, which has a chiral centre next to the silicon atom. The crossed-aldol reaction of the silyl enol ether with benzaldehyde gave the corresponding aldol products with high chirality transfer.
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