Stereoselective One-Pot Synthesis of Functionalised Phosphonates by three-component reaction between Trialkyl(aryl) Phosphites,Dimethyl Acetylenedicarboxylate and indan-1,3-dione or N,N ′-dimethylbarbituric acid
Free accessResearch articleFirst published online August, 2007
Stereoselective One-Pot Synthesis of Functionalised Phosphonates by three-component reaction between Trialkyl(aryl) Phosphites,Dimethyl Acetylenedicarboxylate and indan-1,3-dione or N,N ′-dimethylbarbituric acid
Protonation of the reactive intermediate produced in the reaction between trialkyl(aryl) phosphites and dimethyl acetylenedicarboxylate by CH- acids such as indane-1,3-dione and N,N′-dimethylbarbituric acid leads to functionalised phosphonates in good yields.
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