Pentaisopropoxostannate derivatives of the types [{M[Sn(OPri)5](μ–Cl)}2] and [M{Sn(OPri)5}2] have been prepared by the reactions of MCl2 (M = Mg, Zn, and Cd) with NaSn(OPri)5 in 1:1 and 1:2 molar ratios, respectively, in benzene. All these derivatives have been characterised by elemental and isopropoxo group analyses, spectroscopic (IR, 1H and 13C NMR) studies, and molecular weight determinations. Two typical hydrolytic reactions of [Zn{Sn(OPri)5}2] have also been investigated.
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