New class of macrocyclic aryloxy phosphoranes (10a–d, 11a–d, 12a–d) were prepared by reactants the bifunctional synthons (7–9) with bis(2/3-chloroalkyl)phenyl triester of phosphoric acid (5a–d) in the presence of aq.NaOH in n-BuOH in moderate yields. Their chemical structures were established by analytical and spectral (IR, 1H, 13C and 31P and Mass) data.
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