Abstract
A novel potential bidentate sulfur ligand, K2[S2CNHCOCH2CN] and its complexes with first row divalent transition metal ions of the type, M(phen)L, [M = Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Pd(II), L = S2CNHCOCH2CN and phen = 1,10-phenanthroline] have been synthesised and characterised. On the basis of IR and 1H NMR an enol form is found in the case of ligand and its complexes in the solid state whereas the complexes exist predominantly in the keto form in solution. Electronic spectra and magnetic measurement data indicate that the Ni(II), Cu(II) and Pd(II) complexes have a square-planar geometry but the others have a distorted-tetrahedral structure.
References
1.
Hantzsch A.
, and
Wolvekamp M.
, Ann. , 1904 , 331 , 265 .
2.
Cotton F.A.
, and
Harris C.B.
, Inorg. Chem. , 1968 , 7 , 2140 .
3.
Assefa Z.
,
Staples R.J.
, and
Fackler J.P.
Jr.
, Acta Crystallogr. Sect. C , 1995 , 51 , 2271 .
4.
Casey A.T.
, and
Raynor J.B.
, J. Chem. Soc. Dalton Trans. , 1983 , 2057 .
5.
Spies H.
, and
Johannsen B.
, Inorg. Chim. Acta , 1981 , 48 , 255 .
6.
Fackler J.P.
Jr.
, and
Coucouvanis D.
, J. Am. Chem. Soc. , 1966 , 88 , 3913 .
7.
Cotton F.A.
, and
McCleverty J.A.
, Inorg. Chem. , 1967 , 6 , 229 .
8.
McFadyen W.D.
,
Laurence P.G.W.
,
Roos I.A.G.
, and
Leopold V.A.
, J. Med. Chem. , 1985 , 28 , 1113 .
9.
Brodie C.R.
,
Collins J.G.
, and
Aldrich-Wright J.R.
, J. Chem. Soc. Dalton Trans. , 2004 , 1145 .
10.
Nami S.A.A.
, and
Siddiqi K.S.
, Synth. React. Inorg. Met.-Org. Chem. , 2004 , 34 , 1581 .
11.
Siddiqi K.S.
,
Nami S.A.A.
,
Chebude Y.
, and
Marzotto A.
, J. Chem. Res. , 2006 , 67 .
12.
Siddiqi K.S.
,
Nami S.A.A.
,
Lutfullah
, and
Chebude Y.
, Synth. React. Inorg. Met.-Org. and Nano-Met. Chem. , 2005 , 35 , 445 .
13.
Reilly C.N.
,
Schmid R.W.
, and
Sadek F.S.
, J. Chem. Edu. , 1959 , 36 , 619 .
14.
Geary W.J.
, Coord. Chem. Rev. , 1971 , 7 , 81 .
15.
Seltzer R.
, J. Org. Chem. , 1968 , 33 , 3896 .
16.
Burshell C.J.
,
Aucott S.M.
,
Milton H.L.
,
Slawin A.M.Z.
, and
Woollins J.D.
, J. Chem. Soc. Dalton Trans. , 2004 , 369 .
17.
Mruthyunjayswamy B.H.M.
,
Ijare O.B.
, and
Jadegoud Y.
, J. Braz. Chem. Soc. , 2005 , 16 , 783 .
18.
Nakamato K.
, 4th edn, New-York , John Wiley ,1963 , p. 194 .
19.
Mao H.-Y.
,
Shen X.-Q.
,
Li G.
,
Zhang H.-Y.
,
Xu C.
,
Liu H.-L.
,
Wang E.-B.
,
Hou H.-W.
, and
Zhu Y.
, Polyhedron , 2004 , 23 , 1961 .
20.
Jouad E.M.
,
Allain M.
,
Khan M.A.
, and
Bouet G.M.
, Polyhedron , 2005 , 24 , 327 .
21.
Cotton F.A.
,
Wilkinson G.
,
Murillo C.A.
, and
Bochmann M.
, Advanced Inorganic Chemistry , John Wiley and Sons , New York , 1999 , p. 689 .
22.
Figgis B.N.
, Introduction to Ligand Fields , Wiley Eastern Limited , New Delhi , 1976 , p. 285 .
23.
Kuzniarska-Biernacka I.
,
Bartecki A.
, and
Kurzak K.
, Polyhedron , 2003 , 22 , 997 .
24.
Dingle R.
, Inorg. Chem. , 1968 , 10 , 1141 .
25.
Krishnapriya K.R.
, and
Kandaswamy M.
, Polyhedron , 2005 , 24 , 113 .
26.
Uppadin L.H.
,
Weeks J.M.
, and
Beer P.D.
, J. Chem. Soc. Dalton Trans. , 2001 , 3367 .
27.
Prabhumirashi L.S.
, and
Khoje J.K.
, Ind. J. Chem. 2004 , 43A , 299 .
28.
Mu P.
,
Wang R.
,
Zhao L.
,
Zhu Z.
, and
Guo Y.
, Thermochim. Acta , 1997 , 306 , 77 .
29.
Sharma A.K.
, Thermochim. Acta , 1986 , 104 , 339 .
30.
Rogers M.T.
, and
Burdett J.L.
, Can. J. Chem. , 1965 , 43 , 1516 .
31.
Xu H.
,
Zheng K.
,
Deng H.
,
Lin L.
,
Zhang Q.
, and
Ji L.
, New J. Chem. , 2003 , 27 , 1255 .