Free accessResearch articleFirst published online 2006-8
Bis(chlorine)-1,4-Diazabicyclo[2.2.2]Octane: A Novel and Reusable Oxidising Agent for Conversion of Alcohols into Their Carbonyl Compounds under Microwave Irradiation
Bis(chlorine)-1,4-diazabicyclo[2.2.2]octane was easily prepared by treatment of chlorine gas with 1,4-diazabicyclo [2.2.2]octane at room temperature. It is stable and can be used as an efficient oxidant for aliphatic and aromatic alcohols under microwave irradiation. In the oxidation reactions it is almost quantitatively converted into 1,4-diazabicyclo[2.2.2]octane which can be chlorinated and reused several times.
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