Abstract
Novel Co(III) complexes with general formula, [Co(chel)(PBu3)]ClO4.H2O, where chel = 5-Brsalophen, 5-NO2salophen, 5-MeOsalophen and 4-MeOsalophen, were synthesised and characterised. The spectroscopic and electrochemical properties of these complexes and [Co(salophen)(PR3)]ClO4.H2O (R = PBu3 and PPh3) complexes were investigated.
References
1.
Costamagna J.
,
Vargas J.
,
Latorre R.
,
Alvarado A.
, and
Mena G.
, Coord. Chem. Rev. , 1992 , 119 , 67
2.
Aly M.M.
, J. Cood. Chem. , 1998 , 43 , 89 .
3.
Cmi R.
,
Moore S. J.
, and
Marzilli L. G.
, Inorg. Chem. , 1998 , 37 , 6890 .
4.
Polson S.M.
,
Cini R.
,
Pifferi C.
, and
Marzilli L. G.
, Inorg. Chem. , 1997 , 36 , 314 .
5.
Niederhoffer E.C.
,
Timmons J. H.
, and
Martell A. E.
, Chem. Rev. , 1984 , 84 . 137
6.
Matsuura T.
, Tetrahedron , 1977 , 33 , 2869 .
7.
Nishinaga A.
,
Tsutsui T.
,
Moniyama H.
,
Wazaki T.
,
Mashino T.
, and
Fujii Y. J.
, Mo. Catalysis , 1993 , 83 , 117 .
8.
Nishinaga A.
,
Tsutsui T.
,
Yamazaki S.
, and
Matsuura T.
, Tetrahedron Lett. , 1988 , 29 , 4115 .
9.
Nishinaga A.
,
Ohara H.
,
Tomito H.
, and
Matsuura T.
, Tetrahedron Lett. , 1983 , 24 , 213 .
10.
Eichhorn E.
,
Rieker A.
, and
Speiser B.
, Angw. Chem., Int. Ed. Engl. , 1992 , 31 , 1215 .
11.
Eichhorn E.
,
Rieker A.
, and
Speiser B.
,
Sieglen J.
, and
Strahle J.
, Z. Natureforsch , 1993 , 48b , 418 .
12.
Eichhorn E.
,
Rieker A.
, and
Speiser B.
, and
Stahl H.
, Inorg. Chem. , 1997 , 36 , 3307 .
13.
Eichhorn E.
, and
Speiser B.
, J. Electroanal. Chem. Interfatial Elecrochem. , 1994 , 365 , 207 .
14.
Speiser B.
, and
Stahl H.
, Angw. Chem., Int. Ed. Engl. , 1995 , 34 , 1086 .
15.
Golles B.
,
Speiser B.
,
Stahl H.
,
Sieglen J.
, and
Strahle J.
, Z. Natureforsch , 1996 , 51b , 388 .
16.
Bottcher A.
,
Takeuchi T.
,
Hardcastle I.
,
Mead T. J.
,
Gray H. B.
,
Cwikel D.
,
Kapon M.
, and
Dori Z.
, Inorg. Chem. , 1997 , 36 , 2498 .
17.
Sarvestani A.H.
,
Salimi A.
,
Mohebbi S.
, and
Hallaj R.
, J. Chem. Res. , 2005 , 190 –195 .
18.
Chen H.
,
Cronin J. A.
, and
Archer R. D.
, Inorg. Chem. , 1995 , 34 , 2306 .
19.
Bella S.D.
,
Fragala I.
,
Ledoux I.
,
Diaz-Garcia M. A.
, and
Marks T. J.
, J. Am. Chem. Soc. , 1997 , 119 , 9550 .
20.
Archer R.D.
,
Chen H.
, and
Thompson L. C.
, Inorg. Chem. , 1998 , 37 , 2089 .
21.
Tauzher G.
,
Mestroni G.
,
Puxeddu A.
,
Costanzo R.
, and
Costa G.
, J. Chem. Soc. (A) , 1971 , (A), 2504 .
22.
Smith C.W.
,
Van Loon G. W.
, and
Barid M. C.
, Can. J. Chem. , 1976 , 54 , 1875 .
23.
Asadi M.
,
Sarvestani A. H.
,
Ahmadi M. B.
,
Mohammadi Kh.
, and
Asadi Z.
, J. Chem. Thermodynamics , 2004 , 36 , 141 .
24.
Amirnasr M.
,
Schenk K. J.
,
Gorgji A.
, and
Vafazadeh R.
, Polyhedron , 2001 , 20 , 695 .
25.
Biradar N.S.
,
Karajagi G. V.
, and
Aminabhavi T. M.
, Inorg. Chim. Acta , 1984 , 82 , 211 .
26.
Bertrand J.A.
, and
Eller P. G.
, Inorg. Chem. , 1974 , 4 , 927 .
27.
Estiu G.L.
,
Jubert A. H.
,
Costamagena J.
, and
Vargas J.
, Inog. Chem. , 1996 , 35 , 263 .
28.
Ortiz B.
, and
Park Su-M.
,
Korean Bull
, Chem. Soc. , 2000 , 21 , 4 , 405.