A mononuclear salicylaldehydato copper(II) complex and an infinite 2-aminopyridyl silver(I) coordination polymer have been synthesised by the self-assembly reaction based on the metal-induced hydrolysis of N-salicylidene-2-aminopyridine. The latter chain-like polymer is novel and unavailable under usual reaction conditions. Additionally, an interesting 2D polymeric network is formed from the weak intermolecular interactions.
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