Abstract
The aquation of α-cis-[CoCl2(edda)]- and of β-cis-[CoCl2(trien)]+ has been studied in reverse micelles of water/AOT/n-heptane and water/CTAB/n-heptane+CHCl3 for various concentrations of water and AOT at 298.1 K. The reaction rate depends on the molar ratio W as well as on the concentration of AOT. These results demonstrate the important effect of micelle size as well as of structure and state of confined water in the aquation rate.
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