Abstract
Cobalt (II) and manganese (III) complexes with crowned salicylaldimine mono-Schiff base ligand have been employed as models to mimic hydrolase in catalytic hydrolysis of p-nitrophenyl picolinate(PNPP). The kinetics and the mechanism of PNPP hydrolysis have been investigated. The kinetic mathematical model of PNPP cleavage catalysed by these complexes has been proposed.
Keywords
References
1.
Auld D.S.
, Enzyme Mechanism ,
Page M.I.
, and
Williams A.
, Eds, Ch. 14. Royal Chem. Soc. , London , 1987 .
2.
Vassilev K.
,
Kreider J.
,
Miller P. D.
, and
Ford W. T.
, React. Funct. Polymers , 1999 , 41 , 205 .
3.
You J.S.
,
Yu X. Q.
,
Su X. Y.
, and
Wang T.
, J. Mol. Catal. A: Chemical , 2003 , 202 , 17 .
4.
Rossi L.M.
,
Neves A.
,
Horner R.
, and
Terenzi H.
, Inorg. Chim. Acta , 2002 , 337 , 366 .
5.
Cheng S.Q.
,
Zeng X. C.
,
Meng X. G.
, and
Yu X. Q.
, J. Coll. Interface Sci. , 2000 , 224 , 333 .
6.
Gunnlaugsson T.
,
O'Brien J. E.
, and
Mulready S.
Tetrahedron Lett. , 2002 , 43 , 8493 .
7.
Xiang Q.X.
,
Yu X. O.
, and
Xie R. G.
, Chin. J. Chem. , 2001 19 (2 ), 159 .
8.
Xiang Y.
,
Zeng X. C.
,
Li and T. Y.
,
Xie J. Q.
, J. Coll. Interface Sci. , 2001 , 235 , 114 .
9.
Jiang B.Y.
,
Xiang Y.
,
Xie J. Q.
, and
Zeng X. C.
, Coll. Surfaces A: physicochem. Eng. Aspects. , 2004 , 235 , 145 .
10.
Kou X.M.
,
Meng X. G.
,
Xie J. Q.
, and
Zeng X. C.
, Transit. Met. Chem. , 2003 , 28 , 777 .
11.
Lu X.X.
,
Qin S. Y.
,
Zhou Z. Y.
, and
Yam V. W. W.
, Inorg. Chim. Acta , 2003 , 346 , 49 .
12.
Zeng W.
,
Mao Z. H.
,
Li J. Z.
, and
Qin S. Y.
, J. Supermole. Chem. , 2002 , 2 , 501 .
13.
Zeng W.
,
Li H. B.
,
Wei X. Y.
, and
Qin S. Y.
, Chin. J. Chem. , 2003 , 21 (5 ), 510 .
14.
Can S.
,
Bekâroğlu Ö.
, J. Chem. Soc., Dalton Trans. , 1998 , 2831 .
15.
Endo J.
, J. Chem, Soc. Japan , 1944 , 65 , 428 .
16.
Sigman D.S.
, and
Jorgensen C. T.
, J. Am. Chem. Soc. , 1972 , 94 , 1724 .
17.
Breslow R.
,
McClure D. E.
, and
Brown R. S.
, J. Am. Chem. Soc. , 1975 , 97 , 194 .
